Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (2): 641-649.DOI: 10.6023/cjoc202108023 Previous Articles Next Articles
Special Issue: 有机氟化学虚拟合辑
ARTICLES
锅小龙a, 王玉贤a, 赵志强a, 王庆a, 左剑b,*(), 王陆瑶a,*(
)
收稿日期:
2021-08-16
修回日期:
2021-09-19
发布日期:
2022-02-24
通讯作者:
左剑, 王陆瑶
基金资助:
Xiaolong Guoa, Yuxian Wanga, Zhiqiang Zhaoa, Qing Wanga, Jian Zuob(), Luyao Wanga(
)
Received:
2021-08-16
Revised:
2021-09-19
Published:
2022-02-24
Contact:
Jian Zuo, Luyao Wang
Supported by:
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Xiaolong Guo, Yuxian Wang, Zhiqiang Zhao, Qing Wang, Jian Zuo, Luyao Wang. Electrochemical Oxidative C—H Trifluoromethylation of Quinoxalin-2(1H)-ones and the Performance Evaluation via Electro-descriptors[J]. Chinese Journal of Organic Chemistry, 2022, 42(2): 641-649.
Entry | Variation from the standard reaction conditions | Yieldb/% |
---|---|---|
1 | None | 81 |
2 | No H2O and HOAc | 30 |
3 | No HOAc | 53 |
4 | No H2O | 46 |
5 | DMF instead of CH3CN | Trace |
6 | nBu4NPF6, TBAI and TBAB instead of nBu4NBF4 | 61, 0, 19 |
7 | Pt, RVC instead of C as anode | 44, 0 |
8 | 10 mA, 8 h instead of 20 mA, 4 h | 77 |
9 | 30 mA, 3 h instead of 20 mA, 4 h | 65 |
10 | No electricity | 0 |
Entry | Variation from the standard reaction conditions | Yieldb/% |
---|---|---|
1 | None | 81 |
2 | No H2O and HOAc | 30 |
3 | No HOAc | 53 |
4 | No H2O | 46 |
5 | DMF instead of CH3CN | Trace |
6 | nBu4NPF6, TBAI and TBAB instead of nBu4NBF4 | 61, 0, 19 |
7 | Pt, RVC instead of C as anode | 44, 0 |
8 | 10 mA, 8 h instead of 20 mA, 4 h | 77 |
9 | 30 mA, 3 h instead of 20 mA, 4 h | 65 |
10 | No electricity | 0 |
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