Copper(II) Triflate Chiral Derivatives: Versatile Catalysts for Asymmetric Organic Synthesis1

Abstract

Copper(II) triflate chiral derivatives chelated with bis(oxazoline)s, phosphoramidites, phosphites, phosphonites or other C₂-symmetric chiral ligands have been extensively studied as excellent chiral catalysts in asymmetric synthesis. This review describes in detail the recent advances in the application of these chiral copper(II) catalysts in enantioselective cycloaddition, aldol, conjugate addition, carbonyl-ene and cyclopropanation reactions.

Key words: copper triflate, chiral bis(oxazoline), chiral phosphoramidite, chiral phosphite (phosphonite), asymmetric catalysis

Cite this article

LI Xiao-Yong, WANG Li-Qiong, NIE Jin. Copper(II) Triflate Chiral Derivatives: Versatile Catalysts for Asymmetric Organic Synthesis1[J]. Chinese Journal of Organic Chemistry, 2004, 24(10): 1159-1167.

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