Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (11): 3900-3906.DOI: 10.6023/cjoc202304011 Previous Articles Next Articles
肖朵朵, 张建涛, 周鹏*(
), 刘卫兵*()
收稿日期:2023-04-08
修回日期:2023-06-25
发布日期:2023-07-12
基金资助:
Duoduo Xiao, Jiantao Zhang, Peng Zhou(), Weibing Liu()
Received:2023-04-08
Revised:2023-06-25
Published:2023-07-12
Contact:
E-mail: Supported by:Share
Duoduo Xiao, Jiantao Zhang, Peng Zhou, Weibing Liu. Metal-Free α-C(sp3)—H Methylenation of Aryl Ketones to Form γ-Keto Sulfoxides with Dimethyl Sulfoxide[J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3900-3906.
| Entry | Peroxide | T/℃ | t/h | Yieldb/% |
|---|---|---|---|---|
| 1 | (NH4)2S2O8 | 120 | 5 | 49 |
| 2 | (NH4)2S2O8 | 120 | 7 | 69 |
| 3 | (NH4)2S2O8 | 120 | 9 | 69 |
| 4 | (NH4)2S2O8 | 70 | 7 | — |
| 5 | (NH4)2S2O8 | r.t. | 7 | — |
| 6 | Benzoyl peroxide | 120 | 7 | — |
| 7 | Peroxide isobutylbenzene | 120 | 7 | — |
| 8 | K2S2O8 | 120 | 7 | 15 |
| 9 | DTBP | 120 | 7 | — |
| 10 | TBHP | 120 | 7 | — |
| 11c | (NH4)2S2O8 | 120 | 7 | 54 |
| 12d | (NH4)2S2O8 | 120 | 7 | 77 |
| 13d,e | (NH4)2S2O8 | 120 | 7 | 77 |
| 14d,f | (NH4)2S2O8 | 120 | 7 | 77 |
| Entry | Peroxide | T/℃ | t/h | Yieldb/% |
|---|---|---|---|---|
| 1 | (NH4)2S2O8 | 120 | 5 | 49 |
| 2 | (NH4)2S2O8 | 120 | 7 | 69 |
| 3 | (NH4)2S2O8 | 120 | 9 | 69 |
| 4 | (NH4)2S2O8 | 70 | 7 | — |
| 5 | (NH4)2S2O8 | r.t. | 7 | — |
| 6 | Benzoyl peroxide | 120 | 7 | — |
| 7 | Peroxide isobutylbenzene | 120 | 7 | — |
| 8 | K2S2O8 | 120 | 7 | 15 |
| 9 | DTBP | 120 | 7 | — |
| 10 | TBHP | 120 | 7 | — |
| 11c | (NH4)2S2O8 | 120 | 7 | 54 |
| 12d | (NH4)2S2O8 | 120 | 7 | 77 |
| 13d,e | (NH4)2S2O8 | 120 | 7 | 77 |
| 14d,f | (NH4)2S2O8 | 120 | 7 | 77 |
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