Advances in Catalytic Conversion of CO2 with Carbazole-Based Molecules and Polymers

doi:10.6023/cjoc202311016

Abstract

Carbazole moiety exhibits excellent electron transfer ability due to its rigid planar structure and large conjugate system. The N atom and aromatic ring of carbazole can be easily modified, and carbazole-based ligands and polymers have attracted significant amounts of interests in the fields of catalysis and material sciences. Important progress has been achieved in both homogeneous and heterogeneous catalysis promoted by catalysts containing carbazole as the backbone or linker. The catalytic conversion of carbon dioxide can provide an important technology support for realization of carbon neutrality goals. In this paper, the recent progresses on the use of carbazole-based ligands, carbazole-based complexes or carbazole-based heterogeneous materials in catalytic transformation of CO₂ are reviewed, including the methods of catalyst preparation, the different types of reactions in homogeneous and heterogeneous catalysis. This review will provide systematic information for further understanding the important role of carbazole units in catalysis and designing more efficient carbazole-based materials.

Key words: carbazole structure, carbon dioxide, homogeneous catalysis, heterogeneous catalysis, electron transfer

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Xiaolin Jiang, Chaoyang Wang, Liyuan Wu, Yuehui Li. Advances in Catalytic Conversion of CO₂ with Carbazole-Based Molecules and Polymers[J]. Chinese Journal of Organic Chemistry, 2024, 44(5): 1423-1444.

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Fig. & Tab. 33

Figure 1. Some CNC carbazole pincer ligands and metal complexes

Figure 2. Application of CNC carbazole pincer ligands in poly- merization and cycloaddition reactions

Figure 3. Application of CNC carbazole pincer ligands in cycloaddition reactions

Figure 4. Application of CNC carbazole pincer ligands in catalytic deoxygenation of epoxides

Figure 5. Some PNP carbazole pincer ligands and metal complexes

Figure 6. Reactivity of PNP carbazole pincer T-typed Iron(I) complexes with CO2

Figure 7. Some NNN carbazole pincer ligands and metal complexes

Figure 8. Application of carbazole-phosphine ligands in CO2 reduction formylation and methylation reactions

Figure 9. Application of N-P carbazole ligands in the thiocarbonylation of aryl iodides with CO2

Figure 10. Functionalized carbazole-phosphine ligands and applications in CO2 involved reactions

Figure 11. Application of carbazole-phosphine ligands in the carbonylation of terminal alkyne

Figure 12. Application of carbazole-phosphine ligands in the carbonylation of alkene

Figure 13. Rhenium complexes with 1,10-phenanthroline ligand bearing N-heterocyclic substituents

Figure 14. Application of novel double NHC carbazole nickel complex in CO2 reduction

Figure 15. Some structure of photosensitizer with dicyanobenzene backbone

Figure 16. Mechanism of the carboxylation of C—H bond at the benzyl position catalyzed by 4CzIPN

Figure 17. Photocatalytic reaction involving CO2 using 4CzIPN as a photosensitizer

Figure 18. Application of 4CzIPN-terpyridine-Fe system in CO2 photoreduction

Figure 19. Application of 4CzIPN-terpyridine-metal system in CO2 photoreduction

Figure 20. CO2 photoreduction system without metal catalysts

Figure 21. Application of Re-metalated polypyridine-based porous polycarbazoles in CO2 photoreduction

Figure 22. Application of metalated porous polycarbazole complexes in CO2 photoreduction

Figure 23. Application of carbazole-based polymer metal complexes in CO2 photoreduction

Figure 24. Application of carbazole-based composite metal materials in CO2 photoreduction

Figure 25. Application of carbazole-triazine covalent organic framework in CO2 photoreduction

Figure 26. Application of carbazolyl-based pyridine conjugated organic polymers in CO2 photoreduction

Figure 27. Photoreduction of CO2 with porous organic polymer achieved by copolymerization of photosensitizer and carbazole

Figure 28. Carbazole dendrimer modified Au electrodes for CO2 electroreduction

Figure 29. Carbazole dendrimer modified Au electrodes for CO2 electroreduction

Figure 30. Electrocarboxylation reaction of CO2 achieved Cu-embedded carbazole-derived porous organic polymer nanohybrid

Figure 31. Reductive formylation of CO2 with Pd nanoparticles decorated on hypercrosslinked polymer bearing carbazole

Figure 32. Reaction of CO2 with Ag nanoparticles decorated on hypercrosslinked porous polymer bearing carbazole

Figure 33. Application of carbazole-based covalent triazine frameworks in CO2 cycloaddition reactions

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含咔唑结构的小分子及聚合物催化二氧化碳转化研究进展

Advances in Catalytic Conversion of CO₂ with Carbazole-Based Molecules and Polymers

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