Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (5): 1506-1525.DOI: 10.6023/cjoc202309013 Previous Articles     Next Articles

REVIEWS

二氧化碳参与的三组分偶联反应进展

夏坤a, 张开发a, Sher Wali Khanb, 阿布力米提•阿布都卡德尔a,*()   

  1. a 新疆大学化学学院 碳基能源化学与利用国家重点实验室 乌鲁木齐 830017
    b 拉瓦尔品第女子大学化学系 拉瓦尔品第卫星镇 巴基斯坦 43600
  • 收稿日期:2023-09-13 修回日期:2023-12-19 发布日期:2024-02-07
  • 基金资助:
    新疆省自然科学基金(2022E01069); 新疆省自然科学基金(2020D01C024); 国家自然科学基金(22061040); 国家自然科学基金(21562039)

Advances in Three-Component Coupling Reactions Involving CO2

Kun Xiaa, Kaifa Zhanga, Sher Wali Khanb, Abdukader Ablimita()   

  1. a Key Laboratory of College of Chemistry, Xinjiang University, Urumqi 830000
    b Department of Chemistry, Rawalpindi Women University, Satelite Town of Rawalpindi, Pakistan 43600
  • Received:2023-09-13 Revised:2023-12-19 Published:2024-02-07
  • Contact: *E-mail: ablimit1970@126.com
  • Supported by:
    Xinjiang Natural Science Foundation(2022E01069); Xinjiang Natural Science Foundation(2020D01C024); National Natural Science Foundation of China(22061040); National Natural Science Foundation of China(21562039)

Carbon dioxide (CO2) is the attractive green and renewable C1 resource, and its direct participation in organic synthesis reactions as a reaction feedstock or promoter, which is a research direction advocated by green chemistry. On the other hand, the three-component coupling reaction is considered to be one of the most attractive strategies in synthetic chemistry, which is capable of synthesizing complex molecules directly from simple and readily available raw materials. Based on this, this paper reviews the three-component coupling reaction systems involving CO2 as a raw material or promoter, categorizes them according to the types of products generated: carboxyl, ester, carbonyl, haloalkyl, and cyano compounds as well as CO2 as a promoter. An outlook on the development of such reactions is also given.

Key words: carbon dioxide, green chemistry, three-component coupling, promoter