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About the Cover:The recent progress on the application of sulfoxonium ylides in C—H activation is summarized by Hong, Jiang, Yu, Liu and Zhang on page 888. An overview of the advances of sulfoxonium ylides is given from three aspects: sulfoxonium ylide as a coupling synthon, sulfoxonium ylide as a directing group as well as self-coupling and condensation of sulfoxonium ylide. Finally, the future challenges and developments of sulfoxonium ylides are also prospected.
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About the Cover:Cu(OAc)2-mediated dithiolation of C(sp2)—H bonds with aryl thiols has been developed via using amideoxazoline as directing group to afford functionalized thioethers by Wang, Wang, Song, Huo, Zhou, Kang, and Liu on page 1098. Under the optimized conditions, various substituted phenylamides and pyridine amides were well tolerated to give the corresponding products in good to excellent yields.
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