锂磷氧氮(LiPON)薄膜电解质和全固态薄膜锂电池研究

化学学报 ›› 2004, Vol. 62 ›› Issue (22): 2223-2227. 上一篇下一篇

研究论文

锂磷氧氮(LiPON)薄膜电解质和全固态薄膜锂电池研究

刘文元, 傅正文, 秦启宗

复旦大学化学系激光化学研究所, 上海市分子催化和功能材料重点实验室, 上海, 200433

投稿日期:2004-03-01 修回日期:2004-07-22 发布日期:2014-02-17
通讯作者: 秦启宗,E-mail:qzqin@fudan.ac.cn;Tel:021-65102777;Fax:021-65102777 E-mail:qzqin@fudan.ac.cn
基金资助:
国家自然科学基金(No.20203006)资助项目.

Studies on Lithium Phosphorous Oxynitride Electrolyte Thin Films and a New All-solid-state Thin Film Lithium Battery

LIU Wen-Yuan, FU Zheng-Wen, QIN Qi-Zong

Laser Chemistry Institute & Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai, 200433

Received:2004-03-01 Revised:2004-07-22 Published:2014-02-17

文章分享

摘要/Abstract

采用电子束热蒸发Li₃PO₄与氮等离子体辅助相结合的方法制备了含氮磷酸锂(LiPON)电解质薄膜,已测得该非晶态电解质薄膜在温度为300K时的离子导电率为6.0×10^-7 S/cm,电子电导率低于10^-10 S/cm,电化学稳定窗口为5.0V.以脉冲激光沉积法(PLD)制备的非晶态Ag_0.5V₂O₅薄膜为阴极,真空热蒸发法制备的金属锂为阳极,LiPON薄膜为电解质,成功地制备了一个新的Li/LiPON/Ag_0.5V₂O₅全固态薄膜锂电池.该电池以14μA/cm²电流充/放电时,首次放电容量达到62 μAh·cm^-2·μm^-1,10次循环后容量衰减缓慢,衰减率约为0.2%,循环寿命达到550次以上.

关键词: 薄膜, 电子束蒸发, LiPON, 固体电解质, 锂电池

Lithium phosphorous oxynitride (LiPON) electrolyte thin films have been fabricated by nitrogen plasma-assisted deposition coupled with electron-beam reactive evaporated Li₃PO₄ for the first time. This electrolyte thin film, deposited at the nitrogen plasma reactor power of 350 W, was found to be amorphous with the ionic conduction of 6.0×10^-7 S/cm at 300 K and an electrochemical stable window of 5.0 V. By using the LiPON thin film, a new all-solid-state thin film lithium battery of Li/LiPON/Ag_0.5V₂O₅ has been successfully prepared. The cathode thin film of Ag_0.5V₂O₅ was fabricated using pulsed laser deposition (PLD), and the metallic lithium anode thin film was prepared via vacuum thermal evaporation. For Li/LiPON/Ag_0.5V₂O₅ battery, the open circuit voltage was 3.0 V and the first discharge capacity was 62 μAh·cm^-2·μm^-1 at a current density of 14 μA/cm². After the 10th cycle, the capacity fading was limited to about 0.2% per cycle and this battery could be cycled more than 550 cycles.

Key words: thin film, e-beam evaporation, LiPON, solid electrolyte, lithium battery

引用此文

刘文元, 傅正文, 秦启宗. 锂磷氧氮(LiPON)薄膜电解质和全固态薄膜锂电池研究[J]. 化学学报, 2004, 62(22): 2223-2227.

LIU Wen-Yuan, FU Zheng-Wen, QIN Qi-Zong. Studies on Lithium Phosphorous Oxynitride Electrolyte Thin Films and a New All-solid-state Thin Film Lithium Battery[J]. Acta Chimica Sinica, 2004, 62(22): 2223-2227.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Bates, J. B.; Dudney, N. J.; Lubben, D. C.; Gruzalski, G. R.; Kwak, B. S.; Yu, X.-H.; Zuhr, R. A. J. Power Sources 1995, 54, 58.
[2] Wakihara, M.; Yamamoto, O. Lithium Ion Batteries, Wiley, New York, 1998, p. 180.
[3] Kanehori, K.; Matsumoto, K.; Miyauchi, K.; Kudo, T. Solid State Ionics 1983, 9-10, 1445.
[4] Levasseur, A.; Kbala, M.; Hagenmuller, P.; Couturier, G.; Danto, Y. Solid State Ionics 1983, 9-10, 1439.
[5] Creus, R.; Sarradin, J.; Astier, R.; Pradel, A.; Ribes, M. Mater. Sci. Eng., B 1989, 3, 109.
[6] Bates, J. B.; Dudney, N. J.; Gruzalski, G. R.; Zuhr, R. A.; Choudhury, A.; Luck, C. F. Solid State Ionics 1992, 53, 647.
[7] Yu, X. H.; Bates, J. B.; Jellison, G. E. Jr.; Harl, F. X. J. Electrochem. Soc. 1997, 144, 524.
[8] Wang, B.; Bates, J. B.; Hart, F. X.; Sales, B. C.; Zuhr, R. A.; Robertson, J. D. J. Electrochem. Soc. 1996, 143, 3203.
[9] Vereda, F.; Clay, N.; Gerouki, A.; Goldner, R. B.; Haas, T.; Zerigian, P. J. Power Sources 2000, 89, 201.
[10] Zhao, S. L.; Fu, Z. W.; Qin, Q. Z. Thin Solid Films 2002, 415, 108.
[11] Chu, Y. Q.; Qin, Q. Z. Chem. Mater. 2002, 14, 3152.
[12] Liu, W. Y.; Fu, Z. W.; Li, C. L.; Qin, Q. Z. Electrochem. Solid-State Lett. 2004, 7, J36.
[13] Jamal, M.; Venugopal, G.; Shareefuddin, M.; Chary, M. N. Mater. Lett. 1999, 39, 28.
[14] Lou, Y.-L.; Xiao, W.-K. Electr. Compon. Mater. 2001, 20, 3 (in Chinese).(娄彦良, 肖文凯, 电子元件与材料, 2001, 20, 3.)
[15] Barker J.; Koksbang, R. Solid State Ionics 1995, 78, 161.
[16] Koike, S.; Fujieda, T.; Sakai, T.; Higuchi, S. J. Power Sources 1999, 81, 581.
[17] McGraw, J. M.; Perkins, J. D.; Zhang, J. G.; Liu, P.; Parilla, P. A.; Turner, J. A.; Schulz, D. L.; Curtis, C. J.; Ginley, D. S. Solid State Ionics 1998, 113, 407.
[18] Kim, H. K.; Seong, T. Y.; Yoon, Y. S. J. Vac. Sci. Technol., B 2003, 21, 754.
[19] Jeon, E. J.; Shin, Y. W.; Nam, S. C.; Cho, W. I.; Yoona, Y. S. J. Electrochem. Soc. 2001, 148, 318.

锂磷氧氮(LiPON)薄膜电解质和全固态薄膜锂电池研究

Studies on Lithium Phosphorous Oxynitride Electrolyte Thin Films and a New All-solid-state Thin Film Lithium Battery

PDF

可视化

被引次数

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 15

编辑推荐

相关统计

本文评价

[1]	何文, 王波, 冯晗俊, 孔祥如, 李桃, 肖睿. CO₂捕集膜分离的Pebax基材料研究进展[J]. 化学学报, 2024, 82(2): 226-241.
[2]	郭建荣, 张书玉, 贺军辉, 任世学. 基于生物质可降解薄膜的制备与应用[J]. 化学学报, 2024, 82(2): 242-256.
[3]	苑志祥, 张浩, 胡思伽, 张波涛, 张建军, 崔光磊. 离子聚合原位固态化构建高安全锂电池固态聚合物电解质的研究进展^★[J]. 化学学报, 2023, 81(8): 1064-1080.
[4]	伏成玉, 周星宇, 杨鹏. 基于蛋白质类淀粉样聚集的表面功能化^★[J]. 化学学报, 2023, 81(11): 1566-1576.
[5]	张琪, 江梦云, 刘天一, 曾意迅, 石胜伟. 可蒸镀自旋交叉配合物的薄膜与器件[J]. 化学学报, 2022, 80(9): 1351-1363.
[6]	王洁, 叶雨晴, 李源, 马小杰, 王博. 基于无机纳米材料的抗菌抗病毒功能涂层和薄膜[J]. 化学学报, 2022, 80(9): 1338-1350.
[7]	孙嘉贤, 刘禹廷, 尹志刚, 郑庆东. 基于吸收互补有机半导体本体复合薄膜的高性能柔性光突触晶体管[J]. 化学学报, 2022, 80(7): 936-945.
[8]	曹琳安, 魏敏. 电子导电金属有机框架薄膜的研究进展[J]. 化学学报, 2022, 80(7): 1042-1056.
[9]	闫彬, 薛丁江, 胡劲松. 硒化亚锗薄膜太阳能电池研究进展^※[J]. 化学学报, 2022, 80(6): 797-804.
[10]	张蒙茜, 冯霄. 共轭微孔聚合物膜的制备策略及其分离应用[J]. 化学学报, 2022, 80(2): 168-179.
[11]	孙稷, 易玖琦, 程龙玖. 定向Monte Carlo格点搜索算法用于氧化铝团簇(Al₂O₃)_n (n=1~50)的结构搜索[J]. 化学学报, 2021, 79(9): 1154-1163.
[12]	董锦辉, 李进杰, 王赫, 刘彬秀, 彭博, 陈健壮, 林绍梁. 呼吸图法制备基于准聚轮烷的响应性薄膜[J]. 化学学报, 2021, 79(6): 803-808.
[13]	吴峰, 苏倩倩, 周乐乐, 许鹏飞, 董傲, 钱卫平. 基于二氧化硅胶体晶体薄膜和反射干涉光谱的蛋白冠监测方法[J]. 化学学报, 2021, 79(3): 338-343.
[14]	冯启琨, 张冬丽, 刘畅, 张涌新, 党智敏. 柔性高储能TPU/P(VDF-HFP)全有机复合薄膜的制备及性能表征[J]. 化学学报, 2021, 79(10): 1273-1280.
[15]	田建鑫, 郭慧娟, 万静, 刘桂贤, 严会娟, 文锐, 万立骏. 固态锂电池电极过程的原位研究进展[J]. 化学学报, 2021, 79(10): 1197-1213.