Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (7): 644-649. Previous Articles     Next Articles

Original Articles

铬天青S的液/液界面离子转移过程

孙志胜;汪尔康   

  1. 中国科学院长春应用化学研究所
  • 发布日期:1989-07-15

Ion transfer of chromazurol S across the liquid-liquid interface

SUN ZHISHENG;WANG ERKANG   

  • Published:1989-07-15

The ion transfer of Chromazural S (CAS) across the interface of W/NB and W/1,2-DCE was studied by cyclic voltammetry and chronopotentiometry with linear current scanning. The transfer mechanism of CAS was proposed in terms of its electrochem. behavior and equilibrium of dissociation The experimental data obtained for half-wave potential D0wf1/2 and pH in W phase are in agreement with the theor. equation based on the mechanism proposed. The standard potential differences D0wf0 and standard Gibbs energy of Chrom Azurol S across the interface were calculated

Key words: WATER, NITROBENZENE, CHROME AZUROLS, DICHLOROETHANE, DISSOCIATION EQUILIBRIUM, CHRONOPOTONTIOMETRY, GIBBS FREE ENERGY, CYCLOVOLTAMGRAPH, INTERFACE CHEMISTRY, CURRENT SCANNING

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