有机化学 ›› 2017, Vol. 37 ›› Issue (3): 577-585.DOI: 10.6023/cjoc201609015 上一篇    下一篇

综述与进展

g-C3N4光催化剂在有机合成中的应用

戴小强, 朱亚波, 许孝良, 翁建全   

  1. 浙江工业大学化学工程学院 杭州 310014
  • 收稿日期:2016-09-13 修回日期:2016-11-02 出版日期:2017-03-25 发布日期:2016-11-17
  • 通讯作者: 翁建全,E-mail:jqweng@zjut.edu.cn E-mail:jqweng@zjut.edu.cn
  • 基金资助:

    国家自然科学基金(No.30900959)和浙江省公益性(No.2014C31127)资助项目.

Photocatalysis with g-C3N4 Applied to Organic Synthesis

Dai Xiaoqiang, Zhu Yabo, Xu Xiaoliang, Weng Jianquan   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2016-09-13 Revised:2016-11-02 Online:2017-03-25 Published:2016-11-17
  • Contact: 10.6023/cjoc201609015 E-mail:jqweng@zjut.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 30900959) and the Public Project of Zhejiang Province (No. 2014C31127).

石墨氮化碳(g-C3N4)是一种新型的非金属光催化剂.其2.7 eV的能隙带在可见光区域能被吸收,以及独特的结构赋予其良好的光催化活性,使其在可见光催化领域逐渐被重视.主要综述了该类光催化剂在氧化反应、还原反应、碳-碳键的形成、环化反应等有机反应中的应用,并对其发展进行了展望.

关键词: 石墨氮化碳, 可见光催化, 有机反应

Graphite carbon nitride (g-C3N4) is a new metal-free photocatalyst. Due to its 2.7 eV band gap which makes it being absorbed in the visible region, as well as unique structure which gives it good photocatalytic activity, g-C3N4 has attracted more and more attentions in visible photocatalysis field. The application of photocatalysis with g-C3N4 in organic reactions, such as oxidation reaction, reduction reaction, carbon-carbon bond formation, cyclization reaction and other organic reactions, is summarized and its future outlook is also discussed.

Key words: graphite carbon nitride, visible light catalysis, organic reactions