有机化学 ›› 2018, Vol. 38 ›› Issue (2): 443-450.DOI: 10.6023/cjoc201707018 上一篇    下一篇

研究论文

通过2-萘酚与芳基肼的反应一步构筑非对称的1,1'-二芳基-2,2'-二胺化合物

贾磊, 唐强, 罗美明, 曾小明   

  1. 四川大学化学学院 成都 610064
  • 收稿日期:2017-07-14 修回日期:2017-09-20 出版日期:2018-02-25 发布日期:2017-10-16
  • 通讯作者: 罗美明, 曾小明 E-mail:luomm@scu.edu.cn;zengxiaoming@scu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21321061,21072134,21202128,21572175,J1103315/J0104)资助项目.

One-Step Synthesis of Unsymmetric 1,1'-Biaryl-2,2'-diamines by the Reaction of 2-Naphthols with Aryl Hydrazines

Jia Lei, Tang Qiang, Luo Meiming, Zeng Xiaoming   

  1. College of Chemistry, Sichuan University, Chengdu 610064
  • Received:2017-07-14 Revised:2017-09-20 Online:2018-02-25 Published:2017-10-16
  • Contact: 10.6023/cjoc201707018 E-mail:luomm@scu.edu.cn;zengxiaoming@scu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21321061, 21072134, 21202128, 21572175, J1103315/J0104).

报道了一类无金属参与、操作简单的合成方法来制备非对称的1,1'-二芳基-2,2'-二胺化合物.与已知的三步合成法比较,该策略将2-萘酚与芳基肼反应,不需要使用过渡金属催化剂和配体,具有操作简单、一步合成的优点.

关键词: 1,1'-二芳基-2,2'-二胺, 2-萘酚, 肼, 合成方法

A metal-free, operationally simple synthetic protocol for the buildup of unsymmetric 1, 1'-biaryl-2, 2'-diamine compounds was reported. This reaction was performed by the treatment of 2-naphthols with aryl hydrazines under no transition metal catalyst and no ligand conditions, which has the advantages of simple operation and one-step synthesis.

Key words: 1,1'-biaryl-2,2'-diamine, 2-naphthol, hydrazine, synthetic methodology