有机化学 ›› 2018, Vol. 38 ›› Issue (11): 2807-2832.DOI: 10.6023/cjoc201805031 上一篇    下一篇

所属专题: 有机光催化合辑 有机小分子-金属协同催化

综述与进展

氧杂蒽类有机染料在可见光诱导有机合成中的应用

徐雯秀, 戴小强, 徐涵靖, 翁建全   

  1. 浙江工业大学化学工程学院 杭州 310014
  • 收稿日期:2018-05-15 修回日期:2018-06-15 发布日期:2018-07-16
  • 通讯作者: 翁建全 E-mail:jqweng@zjut.edu.cn
  • 基金资助:

    浙江省自然科学基金(No.LY17C140003)资助项目.

Application of Oxime Organic Dyes in Visible-Light-Induced Organic Synthesis

Xu Wenxiu, Dai Xiaoqiang, Xu Hanjing, Weng Jianquan   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2018-05-15 Revised:2018-06-15 Published:2018-07-16
  • Supported by:

    Project supported by the Natural Science Foundation of Zhejiang Province (No. LY17C140003).

氧杂蒽类有机染料作为光氧化还原催化剂,因具有廉价易得、水溶性好、反应活性高等优点被广泛应用于可见光诱导的有机合成中.其催化的有机反应类型不断被拓展,有逐渐取代部分过渡金属催化剂的趋势.根据反应类型进行分类,综述了近些年几种常用氧杂蒽类有机染料在光诱导有机合成中的研究进展,并对其前景进行了展望.

关键词: 有机染料, 光氧化还原, 有机合成, 过渡金属

Oxime organic dyes, acting as photoredox catalysts, are widely used in visible-light-induced organic synthesis due to their advantages of low cost, good water solubility, high reactivity and so on. The type of organic dyes-catalyzed organic reactions is continuously expanding, and there is a tendency that organic dyes are gradually replacing some of transition metal catalysts. Classified by the type of reactions, the research progress of several common organic dyes in visible-light-induced organic synthesis in recent years is reviewed, and their future outlook is also discussed.

Key words: organic dyes, photoredox, organic synthesis, transition metals