有机化学 ›› 2019, Vol. 39 ›› Issue (11): 3040-3050.DOI: 10.6023/cjoc201904022 上一篇    下一篇

所属专题: 有机光催化合辑

综述与进展

新型光敏剂2, 4, 5, 6-四(9-咔唑基)间苯二腈在无金属有机光合成中的应用

陈锦杨*(), 李玉涵, 梅兰, 吴红谕   

  1. 长江师范学院化学化工学院 重庆涪陵 408000
  • 收稿日期:2019-04-09 发布日期:2019-07-24
  • 通讯作者: 陈锦杨 E-mail:chenjinyang@hnu.edu.cn
  • 基金资助:
    重庆市基础前沿研究(Cstc2018jcyjAX0051)

Application of Photosensitizer 2, 4, 5, 6-Tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene in Photo-induced Transition-Metal-Free Organic Synthesis

Chen Jinyang*(), Li Yuhan, Mei Lan, Wu Hongyu   

  1. College of Chemistry and Chemical Engineering, Yangtze Normal University, Fuling, Chongqing 408000
  • Received:2019-04-09 Published:2019-07-24
  • Contact: Chen Jinyang E-mail:chenjinyang@hnu.edu.cn
  • Supported by:
    the Basic and Frontier Research Project of Chongqing City(Cstc2018jcyjAX0051)

可见光促进的有机合成是近年来有机化学领域重要的研究热点和前沿.其中,廉价易得的有机染料作为光催化剂的应用引起了人们的关注.近来,2,4,5,6-四(9-咔唑基)间苯二腈(4CzIPN)作为一种新型的有机光敏剂,在可见光诱导的自由基反应中表现出优异的催化性能.主要综述了可见光诱导下4CzIPN催化的无金属有机光合成反应,介绍了4CzIPN引发不同类型自由基前体(包括硅试剂、羧酸及其衍生物、含硫试剂和氟试剂等)的光合成应用.

关键词: 2, 4, 5, 6-四(9-咔唑基)间苯二腈(4CzIPN), 有机光催化剂, 可见光诱导, 无金属

Visible-light-promoted organic synthesis is an important research hotspot and frontier in organic chemistry in recent years. Particularly, as a novel organic photosensitizer, 2, 4, 5, 6-tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene (4CzIPN) has showed excellent catalytic performance in visible-light-induced radical reactions. The recent progress on the transition-metal-free photosynthesis under visible-light catalyzed by 4CzIPN is reviewed, and the application of 4CzIPN for photocatalytic organic transformations from different precursors (including silicon reagent, carboxylic acid and its derivatives, sulfur-containing reagent and fluorine reagent) is included.

Key words: 2, 4, 5, 6-tetrakis(carbazol-9-yl)-1, 3-dicyanobenzene (4CzIPN), organophotocatalyst, visible-light-induced, metal-free