有机化学 ›› 1999, Vol. 19 ›› Issue (1): 63-67. 上一篇    下一篇

研究论文

N-芳亚甲基-1-丙烯-1-胺与醇钠的反应

陈林;姚子鹏   

  1. 云南民族学院化学系;复旦大学化学系.上海(200433)
  • 发布日期:1999-02-25

Reaction of N-arylmethylene-1-propen-1-amines with sodium alkoxide

Chen Lin;Yao Zipeng   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:1999-02-25

研究了N-芳亚甲基-1-丙烯-1-胺与醇钠(甲醇钠,乙醇钠)的加成反应,该反应具有高度的区域选择性,提出了可能的反应机理。

关键词: 氮杂二烯, 反应机理, 甲醇钠, 红外分光光度法, 质子磁共振谱法, 加成反应, 乙醇钠, 丙烯P, 丙烯胺P, 醇钠

The reaction between N-arylmethylene-1-propen-1-amine (2) and sodium alkoxide (NaOMe, NaOEt) was studied. The reaction formed regioselectively imines (3). A plausible mechanism was proposed.

Key words: INFRARED SPECTROPHOTOMETRY, PROPENAMINE P, PROTON MAGNETIC RESONANCE SPECTROMETRY, ADDITION REACTION, SODIUM METHOXIDE, REACTION MECHANISM, SODIUM ALCOHOLATE (=SODIUM ALKOXIDE), SODIUM ETHOXIDE, PROPENE P

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