金属有机框架物催化有机反应综述

doi:10.6023/cjoc201601028

摘要/Abstract

金属有机框架物（MOFs）是近十多年发展起来的一类新型有机-无机杂化材料，由有机配体和无机金属单元构建而成，一般具有多变的拓扑结构以及独特的物理化学性质. MOFs具有特殊的孔洞框架结构，材料种类繁多，比表面积大，其孔穴的大小、形状及构成等可以通过选择不同配体和金属离子，或者改变合成策略加以调节. 构成MOFs的配体可以是有机酸，也可以是有机碱，还可以是其他特殊的结构，除此之外在配体上也可以连接特殊官能团，制备具有特殊功能的MOFs材料. 由于MOFs具有特殊而又多种多样的结构，因此在功能材料、气体吸附、药物缓释、催化及有机合成等方面有广泛的应用. 本文以形成MOFs的金属为分类就近十年来各种MOFs的制备及其在催化有机反应中的应用进行了综述，并对其未来研究加以展望.

关键词: 金属有机框架物(MOFs), 制备, 多相催化, 有机合成, 应用

Metal organic frameworks (MOFs) as a new type of organic/inorganic hybrid materials have attracted great focus of scientists in almost twenty years. It is composed of organic ligands and inorganic metal units and generally has a varied topological structure and unique physical/chemical properties. Due to its porous frame structure, large specific surface area and great variety, MOFs are widely used in functional materials, gas adsorption, drug sustained release, catalysis and organic synthesis. It can choose different ligands and metal ions, or change the strategy of synthesis to adjust the size, shape and structure of porous structure. The different ligands can determine the different structure and then affect the properties of MOFs. In this review, the preparation of particular functional MOFs structure and the application of various MOFs in organic synthesis and catalytic organic reactions are reviewed in detail. The summary and prospects about MOFs catalyzed organic reactions and the applications are proposed.

Key words: metal organic frameworks (MOFs), preparation, heterogeneous catalysis, organic synthesis, application

引用此文

徐光利, 刚芳莉, 董涛生, 傅颖, 杜正银. 金属有机框架物催化有机反应综述[J]. 有机化学, 2016, 36(7): 1513-1527.

Xu Guangli, Gang Fangli, Dong Taosheng, Fu Ying, Du Zhengyin. Application of Metal Organic Frameworks in Catalytic Organic Reactions[J]. Chin. J. Org. Chem., 2016, 36(7): 1513-1527.

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