含氮原子桥联吡咯基稀土金属双核配合物的合成及催化e-己内酯的开环聚合反应

doi:10.6023/cjoc201908010

有机化学 ›› 2020, Vol. 40 ›› Issue (3): 801-805.DOI: 10.6023/cjoc201908010 上一篇下一篇

研究简报

含氮原子桥联吡咯基稀土金属双核配合物的合成及催化e-己内酯的开环聚合反应

吴杰, 张秀丽, 张丽军, 韦芸, 周双六

安徽师范大学化学与材料科学学院功能分子固体教育部重点实验室分子基材料安徽省重点实验室安徽芜湖 241002

收稿日期:2019-08-06 修回日期:2019-10-13 发布日期:2019-11-01
通讯作者: 张丽军, 周双六 E-mail:zljun@ahnu.edu.cn;slzhou@ahnu.edu.cn
基金资助:
国家自然科学基金（Nos.21672004，21602004）资助项目.

Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone

Wu Jie, Zhang Xiuli, Zhang Lijun, Wei Yun, Zhou Shuangliu

Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000

Received:2019-08-06 Revised:2019-10-13 Published:2019-11-01
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21672004, 21602004).

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摘要/Abstract

RE（CH₂SiMe₃）₃（THF）₂和1.5 equiv.（C₄H₃NHCH₂）₂NCH₃（1）反应合成得到含氮原子桥联吡咯基稀土金属双核配合物[η¹：η¹：η¹-（C₄H₃NCH₂）₂NCH₃]RE{m-η⁵：η⁵：η¹-（C₄H₃NCH₂）₂NCH₃}RE[η¹：η¹：η¹-（C₄H₃NCH₂）₂NCH₃]（THF）[RE=Y（2），Er（3），Yb（4）]，所得配合物经过核磁共振、红外和元素分析表征，配合物2和4经单晶X-Ray进一步确认结构.同时研究了稀土配合物作为单一组分催化剂催化e-内酯的开环聚合反应.

关键词: 稀土金属, 配合物, e-己内酯, 开环聚合

Reaction of RE(CH₂SiMe₃)₃(THF)₂ with 1.5 equiv. of (C₄H₃NHCH₂)₂NCH₃ (1) in toluene gave nitrogen-containing bridged dipyrrolyl dinuclear rare-earth metal complexes[η¹:η¹:η¹-(C₄H₃NCH₂)₂NCH₃]RE{m-η⁵:η¹:η⁵:η¹:η¹-(C₄H₃NCH₂)₂N-CH₃}RE[η¹:η¹:η¹-(C₄H₃NCH₂)₂NCH₃](THF)[RE=Y (2), Er (3), Yb (4)]. All complexes were fully characterized by spectroscopic methods and elemental analyses. The structures of complexes 2 and 4 were further determined by single-crystal X-ray diffraction. The catalytic properties of rare-earth metal complexes on the ring-opening polymerization of e-caprolactone have been studied.

Key words: rare-earth metal, complex, e-caprolactone, ring-opening polymerization

引用此文

吴杰, 张秀丽, 张丽军, 韦芸, 周双六. 含氮原子桥联吡咯基稀土金属双核配合物的合成及催化e-己内酯的开环聚合反应[J]. 有机化学, 2020, 40(3): 801-805.

Wu Jie, Zhang Xiuli, Zhang Lijun, Wei Yun, Zhou Shuangliu. Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone[J]. Chinese Journal of Organic Chemistry, 2020, 40(3): 801-805.

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含氮原子桥联吡咯基稀土金属双核配合物的合成及催化e-己内酯的开环聚合反应

Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone

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