铁、钴、铜酞菁催化2-氨基苯甲醇氧化制备喹唑啉和喹啉

doi:10.6023/cjoc202003068

摘要/Abstract

酞菁金属络合物在空气中催化2-氨基苄醇与腈和酮的氧化缩合反应，分别制得喹唑啉和喹啉.经过系统研究发现，铁（II）酞菁在喹唑啉合成中显示出较高的催化活性，而铜（II）酞菁在喹啉制备中显示出较高的催化活性.在优化的条件下，各种腈和酮具有良好的适应性，从而以高收率得到相应的产物.

关键词: 金属酞菁, 喹唑啉, 喹啉, 有氧氧化

Phathalocyanine metal complexes catalyzed oxidative condensation of 2-aminobenzyl alcohols with nitriles and ketones has been developed under air to afford quinazolines and quinolines, respectively. After systematic investigation, iron(II) phathalocyanine displayed higher catalytic activity in quinazoline synthesis and copper(II) phathalocyanine showed higher efficiency in quinoline preparation. Under the optimized conditions, various nitriles and ketones were well adaptted to give the corresponding products in good yields.

Key words: phathalocyanine metal complexes, quinazolines, quinolines, aerobic oxidation

引用此文

刘子琳, 张小洁, 张恒, 姜辉, 赵雪梅, 石林林, 朱新举, 郝新奇, 宋毛平. 铁、钴、铜酞菁催化2-氨基苯甲醇氧化制备喹唑啉和喹啉[J]. 有机化学, 2020, 40(9): 2755-2763.

Liu Zilin, Zhang Xiaojie, Zhang Heng, Jiang Hui, Zhao Xuemei, Shi Linlin, Zhu Xinju, Hao Xinqi, Song Maoping. Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino-benzyl Alcohols to Access Quinazolines and Quinolines[J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2755-2763.

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