Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (1): 246-250.DOI: 10.6023/cjoc201405039 Previous Articles     Next Articles



孙京a, 彭新华a, 郭浩b   

  1. a 南京理工大学化工学院 南京 210094;
    b 复旦大学化学系 上海 200433
  • 收稿日期:2014-05-29 修回日期:2014-08-11 发布日期:2014-09-09
  • 通讯作者: 彭新华, 郭浩;
  • 基金资助:


Photoinduced α-C—H Bond Functionalization of Linear Ethers

Sun Jinga, Peng Xinhuaa, Guo Haob   

  1. a School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094;
    b Department of Chemistry, Fudan University, Shanghai 200433
  • Received:2014-05-29 Revised:2014-08-11 Published:2014-09-09
  • Supported by:

    Project supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (No.【45-5】).

A new and effective method for the direct functionalization of ethereal C—H bond was reported. This reaction undergoes smoothly under UV irradiation at room temprature without any additive, which presents a new environmentally friendly protocol to access β-hydroxyl ethers highly selectively. In addition, a possible mechanism of this reaction was proposed.

Key words: photochemistry, C-H functionalization, mechanism, radical reactions, green chemistry