Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (9): 2011-2023.DOI: 10.6023/cjoc201605004 Previous Articles     Next Articles



唐小齐a,b, 谢立波b, 陈雅丽a, 田平b, 林国强b   

  1. a 上海大学化学系 上海 200444;
    b 中国科学院上海有机化学研究所 天然产物有机合成化学重点实验室 上海 200032
  • 收稿日期:2016-05-04 修回日期:2016-05-23 发布日期:2016-05-24
  • 通讯作者: 陈雅丽, 田平;
  • 基金资助:


Recent Progress on Cu-Catalyzed Conjugate Silylation to Unsaturated Compounds

Tang Xiaoqia,b, Xie Libob, Chen Yalia, Tian Pingb, Lin Guoqiangb   

  1. a Department of Chemistry, Shanghai University, Shanghai 200444;
    b CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2016-05-04 Revised:2016-05-23 Published:2016-05-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos.21372243, 21572251, 21572253).

Organosilicon compounds have a wide range of applications in organic synthesis. It can be readily converted to a series of functional compounds through a simple operation. In the recent years, copper-catalyzed conjugate silylation of unsaturated compounds has emerged as a novel synthetic tool to introduce a variety of organosilicon compounds. Herein, this research progress, especially the development in the asymmetric conjugate silylation is summarized.

Key words: copper, unsaturated compounds, asymmetric, conjugate silylation