Recent Progress on Cu-Catalyzed Conjugate Silylation to Unsaturated Compounds

doi:10.6023/cjoc201605004

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (9): 2011-2023.DOI: 10.6023/cjoc201605004 Previous Articles Next Articles

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铜催化的共轭硅化反应的研究进展

唐小齐^a,b, 谢立波^b, 陈雅丽^a, 田平^b, 林国强^b

a 上海大学化学系上海 200444;
b 中国科学院上海有机化学研究所天然产物有机合成化学重点实验室上海 200032

收稿日期:2016-05-04 修回日期:2016-05-23 发布日期:2016-05-24
通讯作者: 陈雅丽, 田平 E-mail:ylchen@staff.shu.edu.cn;tianping@sioc.ac.cn
基金资助:
国家自然科学基金（Nos.21372243，21572251，21572253）资助项目.

Recent Progress on Cu-Catalyzed Conjugate Silylation to Unsaturated Compounds

Tang Xiaoqi^a,b, Xie Libo^b, Chen Yali^a, Tian Ping^b, Lin Guoqiang^b

a Department of Chemistry, Shanghai University, Shanghai 200444;
b CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2016-05-04 Revised:2016-05-23 Published:2016-05-24
Supported by:
Project supported by the National Natural Science Foundation of China (Nos.21372243, 21572251, 21572253).

Organosilicon compounds have a wide range of applications in organic synthesis. It can be readily converted to a series of functional compounds through a simple operation. In the recent years, copper-catalyzed conjugate silylation of unsaturated compounds has emerged as a novel synthetic tool to introduce a variety of organosilicon compounds. Herein, this research progress, especially the development in the asymmetric conjugate silylation is summarized.

Key words: copper, unsaturated compounds, asymmetric, conjugate silylation

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Tang Xiaoqi, Xie Libo, Chen Yali, Tian Ping, Lin Guoqiang. Recent Progress on Cu-Catalyzed Conjugate Silylation to Unsaturated Compounds[J]. Chin. J. Org. Chem., 2016, 36(9): 2011-2023.

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铜催化的共轭硅化反应的研究进展

Recent Progress on Cu-Catalyzed Conjugate Silylation to Unsaturated Compounds

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