Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (6): 1309-1321.DOI: 10.6023/cjoc201701031 Previous Articles     Next Articles

Special Issue: 热点论文合辑

Reviews

二氧化碳参与的环化反应最新研究进展

张文珍, 张宁, 郭春晓, 吕小兵   

  1. 大连理工大学精细化工国家重点实验室 大连 116024
  • 收稿日期:2017-01-14 修回日期:2017-03-19 发布日期:2017-04-01
  • 通讯作者: 张文珍 E-mail:zhangwz@dlut.edu.cn
  • 基金资助:

    中央高校基本科研业务费专项资金(No.DUT15LAB21)和教育部长江学者与创新团队发展计划(Nos.T2011056,IRT13008)资助项目.

Recent Progress in the Cyclization Reactions Using Carbon Dioxide

Zhang Wenzhen, Zhang Ning, Guo Chunxiao, Lü Xiaobing   

  1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024
  • Received:2017-01-14 Revised:2017-03-19 Published:2017-04-01
  • Contact: 10.6023/cjoc201701031 E-mail:zhangwz@dlut.edu.cn
  • Supported by:

    Project supported by the Fundamental Research Funds for the Central Universities (No. DUT15LAB21) and the Program for Changjiang Scholars and Innovative Research Team in University (Nos. T2011056, IRT13008).

Carbon dioxide is a cheap, abundant and renewable C1 feedstock. Methodology study on the transformation of carbon dioxide into highly value-added chemicals has become one of the most active topics in organic chemistry. Owing to the diversity of cyclization reaction and vast occurrence of various heterocyclic motifs in biologically important molecules, the cyclization reactions using carbon dioxide have gained much attention. This review therefore aims to principally describe the recent progress in the new cyclization reactions using carbon dioxide as feedstock to synthesize lactams, lactones, cyclic anhydrides, benzothiazoles, benzimidazoles and other heterocyclic compounds.

Key words: carbon dioxide, cyclization reaction, green chemistry, organic synthesis, heterocycles