Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 1907-1916.DOI: 10.6023/cjoc201801013 Previous Articles     Next Articles

Reviews

基于全氟烷基磺酰亚胺催化剂合成、固载及催化应用研究进展

洪梅, 闵洁, 王石发   

  1. 南京林业大学化工学院 江苏省生物质绿色燃料与化学品重点实验室 南京 210037
  • 收稿日期:2018-01-08 修回日期:2018-03-30 出版日期:2018-08-25 发布日期:2018-05-03
  • 通讯作者: 洪梅, 王石发 E-mail:hongmei-613@njfu.edu.cn;wangshifa65@126.com
  • 基金资助:

    江苏省自然科学基金(No.BK20140969)、江苏高校优势学科建设工程(PAPD)和江苏省生物质能源与材料重点实验室开放基金(No.JSBEM201603)资助项目.

Research Progress of the Synthesis, Immobilization Bis(perfluoro-alkylsulfonyl)imide-Based Complexes and Application in Heterogeneous Catalysis

Hong Mei, Min Jie, Wang Shifa   

  1. Jiangsu Key Laboratory of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037
  • Received:2018-01-08 Revised:2018-03-30 Online:2018-08-25 Published:2018-05-03
  • Contact: 10.6023/cjoc201801013 E-mail:hongmei-613@njfu.edu.cn;wangshifa65@126.com
  • Supported by:

    Project supported by the Natural Science Foundation of Jiangsu Province (No. BK20140969), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and the Open Fund of Jiangsu Key Laboratory of Biomass Energy and Materials (No. JSBEM201603).

Traditional liquid acid catalysts have environmental problems during their application. Perfluoroalkylsulfonylimide complexes show a wide application in catalysis due to their special anionic structures and super acid properties. The structures and properties of bis(perfluoroalkylsulfonyl)imide complexes are introduced. The synthesis and immobilization methods of bis(perfluoroalkylsulfonyl)imide complexes are summarized. The use of immobilized bis(perfluoroalkylsulfonyl)imide complexes in catalytic reactions is also reviewed. The development trends of perfluoroalkylsulfonylimide complexes in the catalytic application are prospected.

Key words: bis(perfluoroalkylsulfonyl)imide, synthesis, immobilization, catalysis