Chinese Journal of Organic Chemistry ›› 2019, Vol. 39 ›› Issue (11): 3065-3083.DOI: 10.6023/cjoc201905016 Previous Articles     Next Articles

可见光诱导的无过渡金属催化交叉脱氢偶联反应研究进展

孔瑶蕾, 徐雯秀, 叶飞霞, 翁建全*()   

  1. 浙江工业大学化学工程学院 杭州 310014
  • 收稿日期:2019-05-09 出版日期:2019-11-25 发布日期:2019-07-09
  • 通讯作者: 翁建全 E-mail:jqweng@zjut.edu.cn
  • 基金资助:
    浙江省自然科学基金(LY17C140003)

Recent Advances in Visible-Light-Induced Cross Dehydrogenation Coupling Reaction under Transition Metal-Free Conditions

Kong Yaolei, Xu Wenxiu, Ye Feixia, Weng Jianquan*()   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2019-05-09 Online:2019-11-25 Published:2019-07-09
  • Contact: Weng Jianquan E-mail:jqweng@zjut.edu.cn
  • Supported by:
    the Natural Science Foundation of Zhejiang Province(LY17C140003)

The cross dehydrogenation coupling reaction realizes direct coupling of two different X-H bonds to form a new chemical bond, thus featuring excellent step and atom economy. The traditional cross dehydrogenation coupling reaction was usually catalyzed by transition metal, which had the problems of expensive catalyst and serious pollution. Visible light-induced electron transfer is also an effective way to realize direct functionalization of X-H bonds. Visible-light-induced cross dehydrogenation coupling reaction under transition metal-free conditions is widely concerned due to the advantages of cleanliness, safety as well as high step and atom economy. Classified by the type of bonding, the research progress of these reactions is reviewed, and their future outlook is also discussed.

Key words: cross dehydrogenation coupling, visible-light-induced, transition metal-free, functionalization