Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (12): 4766-4772.DOI: 10.6023/cjoc202109044 Previous Articles     Next Articles

ARTICLES

N-无保护苯胺电化学硒醚化反应构建4-(烃基硒代)苯胺

李文艺a, 唐胤恒a, 欧阳文韬b, 陆雨函b, 陈锦杨b,*(), 何卫民b,*()   

  1. a 衡阳师范学院化学与材料科学学院 湖南衡阳 421000
    b 南华大学化学化工学院 湖南衡阳 421001
  • 收稿日期:2021-09-28 修回日期:2021-10-30 发布日期:2021-11-03
  • 通讯作者: 陈锦杨, 何卫民
  • 基金资助:
    国家自然科学基金(21902014); 国家自然科学基金(22002037); 湖南省教育厅科学研究(19A068)

Electrochemical Selenylation of N-Unprotected Anilines for Consturcing 4-(Organylselanyl)anilines

Wenyi Lia, Yinheng Tanga, Wentao Ouyangb, Yuhan Lub, Jinyang Chenb(), Weimin Heb()   

  1. a College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421000
    b School of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan 421001
  • Received:2021-09-28 Revised:2021-10-30 Published:2021-11-03
  • Contact: Jinyang Chen, Weimin He
  • Supported by:
    National Natural Science Foundation of China(21902014); National Natural Science Foundation of China(22002037); Scientific Research Hunan Provincial Education Department(19A068)

A transition-metal-free and chemical oxidant-free method was developed for the uniform synthesis of 4-arylselanylanilines and 4-alkylselanylanilines through electrolytic selenylation of N-unprotected anilines with diorganyl diselenides under mild conditions in an undivided cell. The present approach had good functional group compatibility, which made it to be a green and practical method to synthesize 4-(organylselanyl)anilines.

Key words: N-unprotected anilines, diorganyl diselenides, electrochemical synthesis, mild conditions, green chemistry