Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (12): 4257-4274.DOI: 10.6023/cjoc202206003 Previous Articles     Next Articles



窦谦a,b, 汪太民a,*(), 李嗣锋a, 房丽晶a,b, 翟宏斌a,c, 程斌a,*()   

  1. a 深圳职业技术学院 海洋生物医药研究院/博士后创新实践基地 广东深圳 518055
    b 中国科学院深圳先进技术研究院 生物医药与技术研究所 广东深圳 518055
    c 北京大学深圳研究生院 肿瘤化学基因组学国家重点实验室 广东深圳 518055
  • 收稿日期:2022-06-02 修回日期:2022-07-13 发布日期:2022-08-10
  • 通讯作者: 汪太民, 程斌
  • 基金资助:
    广东省教育厅产教融合创新平台(2021CJPT014); 广东省教育厅创新团队(2022KCXTD054); 深圳职业技术学院深圳市高端人才科研启动(6022310047k); 深圳市科技创新委员会(JSGG20201103153800002); 深圳市科技创新委员会(GJHZ20200731095412037); 深圳市科技创新委员会(JCYJ20200109141808025); 深圳职业技术学院博士后基金(6021330006K)

Recent Advances in Photocatalytic Carboxylation with CO2 via σ-Bond Cleavage

Qian Doua,b, Taimin Wanga(), Sifeng Lia, Lijing Fanga,b, Hongbin Zhaia,c, Bin Chenga()   

  1. a Institute of Marine Biomedicine, Postdoctoral Innovation Practice Base, Shenzhen Polytechnic, Shenzhen, Guangdong 518055
    b Institute of Biomedicine and Biotechnology, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong 518055
    c State Key Laboratory of Chemical Oncogenomics, Peking University Shenzhen Graduate School, Shenzhen, Guangdong 518055
  • Received:2022-06-02 Revised:2022-07-13 Published:2022-08-10
  • Contact: Taimin Wang, Bin Cheng
  • Supported by:
    Innovation Platform for the Integration of Production and Education of Guangdong Provincial Education Department(2021CJPT014); Innovation Team of Guangdong Education Department(2022KCXTD054); Scientific Research Startup Fund for Shenzhen High-Caliber Personnel of Shenzhen Polytechnic(6022310047k); Shenzhen Science and Technology Innovation Committee(JSGG20201103153800002); Shenzhen Science and Technology Innovation Committee(GJHZ20200731095412037); Shenzhen Science and Technology Innovation Committee(JCYJ20200109141808025); Post-doctoral Foundation Project of Shenzhen Polytechnic(6021330006K)

Carbon dioxide (CO2), as the main components of greenhouse gases, is one of the most abundant carbon sources at present. In organic chemistry, CO2 is often used as C1 synthon to synthesize carboxylic acids by constructing C—C bond. Transition metal catalysis has developed as a powerful tool for the conversion and utilization of CO2. In order to achieve the strategic goal of “double carbon”, it is of great significance to develop green and sustainable CO2 conversion and utilization technology combined with contemporary hot topics in the field of organic chemistry. In recent years, the development of photocatalytic synthesis technology provied a new opportunity for the conversion and utilization of CO2. The bond breaking of C—H bond, C—O bond, C—N and C—X bond and carboxylation reactions with CO2 by photocatalysis strategy were systematically described.

Key words: photocatalysis, CO2, σ-bond cleavage, carboxylation