Advance in Tetrathiafulvalene and Its Derivatives as  Molecular Switches

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (01): 34-43. Previous Articles Next Articles

Review

四硫富瓦烯及其衍生物在分子开关领域的研究进展

朱玉兰^*,a,b ; 周鑫鑫^a,b ; 尹起范^a ; 曹丽^a

(a淮阴师范学院化学系江苏省低维材料化学重点建设实验室淮安 223300)
(b延边大学理学院化学系延吉 133002)

收稿日期:2008-01-24 修回日期:2008-04-30 发布日期:2009-01-20
通讯作者: 朱玉兰

Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches

Zhu, Yulan^*,a,b; Zhou, Xinxin ^a,b; Yin, Qifan^a; Cao, Li^a

(a Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, Department of Chemistry, Huaiyin Teacher’s College, Huai’an 223300)
(b Department of Chemistry, College of Science, Yanbian University, Yanji 133002)

Received:2008-01-24 Revised:2008-04-30 Published:2009-01-20
Contact: Zhu, Yulan

Abstract

Tetrathiafulvalene (TTF) and its derivatives can be reversibly transformed into the radical cation TTF•+ and dication TTF2＋ through either chemical or electrochemical oxidation. By using of this feature, TTF and its derivatives have been widely investigated for their potential use in molecular switches, molecular sensors, optical information storage and nonlinear optics etc. This article reviews the recent progress in TTF and its derivatives as molecular switches such as fluorescence switch, photochromism switch, chiral switch and supramolecular switch.

Key words: synthesis, molecular switch, molecular recognition, tetrathiafulvalene

Cite this article

Zhu, Yulan^*,a,b; Zhou, Xinxin ^a,b; Yin, Qifan^a; Cao, Li^a. Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches[J]. Chin. J. Org. Chem., 2009, 29(01): 34-43.

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四硫富瓦烯及其衍生物在分子开关领域的研究进展

Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches

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