Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (12): 1463-1472. Previous Articles     Next Articles




  1. (大连理工大学精细化工国家重点实验室 大连 116012)
  • 收稿日期:2006-12-28 修回日期:2007-03-09 发布日期:2007-12-04
  • 通讯作者: 冯秀娟,包明

Cross-Coupling Reactions Catalyzed by Palladium in Supercritical Carbon Dioxide

ZHANG Tao, FENG Xiu-Juan*, WANG Chun-Xia, BAO Ming*   

  1. (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012)
  • Received:2006-12-28 Revised:2007-03-09 Published:2007-12-04
  • Contact: FENG Xiu-Juan, BAO Ming

The construction of new carbon-carbon bond is very important in organic synthesis. The supercritical carbon dioxide has attracted considerable attention because it can be used as an environmentally benign medium for organic reactions. In this paper, palladium catalyzed cross-coupling reactions to form new carbon-carbon bond including Heck reaction, Suzuki reaction, Stille reaction as well as Sonogashira reaction, proceeded in supercritical carbon dioxide are reviewed.

Key words: palladium catalysis, carbon-carbon bond formation, supercritical carbon dioxide