Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (4): 812-824.DOI: 10.6023/cjoc201708019 Previous Articles     Next Articles

Reviews

Pd催化下烯烃、炔烃及芳烃的氧化偶联反应研究进展

徐利革, 黄亿, 刘炳艮, 牛云宏, 火星   

  1. 兰州大学化学化工学院 兰州 730000
  • 收稿日期:2017-08-09 修回日期:2017-09-18 出版日期:2018-04-24 发布日期:2017-10-24
  • 通讯作者: 火星 E-mail:huox@lzu.edu.cn
  • 基金资助:

    国家自然科学基金青年基金(No.21202068)资助项目.

Progress in Oxidative Coupling Reaction of Olefins, Alkynes and Aromatic Hydrocarbons Catalyzed by Palladium

Xu Lige, Huang Yi, Liu Binggen, Niu Yunhong, Huo Xing   

  1. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000
  • Received:2017-08-09 Revised:2017-09-18 Online:2018-04-24 Published:2017-10-24
  • Contact: 10.6023/cjoc201708019 E-mail:huox@lzu.edu.cn
  • Supported by:

    Project supported by the National Science Foundation for Young Scientists of China (No. 21202068).

In 1967, Fujiwara and Moritani reported a type of cross coupling reaction where an aromatic C-H bond is directly coupled to an olefinic C-H bond, generating a new C-C bond in the first time. This reaction is performed in the presence of a transition metal, and typically palladium. In the next few decades, palladium-catalyzed oxidative coupling reactions have become an important method in organic synthesis, and a lot of achievements in scientific research have emerged in the relevant areas. The progress in oxidative coupling reaction of olefins, alkynes and aromatic hydrocarbons catalyzed by palladium is reviewed.

Key words: palladium, oxidative coupling, aryl olefin, alkene