Porous Organic Polymers as Heterogeneous Catalysts for Visible Light-Induced Organic Transformations

doi:10.6023/cjoc202003070

Abstract

The recent applications of porous organic polymers (POPs) as heterogeneous catalysts for visible light-induced organic transformations are summarized. POPs are constructed from conjugated organic monomers, having the features of convenient synthesis and characterization, high stability for quick recovery and reuse, structural diversity as well as high modifiability. POPs possess rigid conjugated frameworks, relatively large surface areas, tunable porosity and typically insoluble in water or organic solvents, and thus ideal platforms for the development of heterogeneous catalysts. Through incorporating conjugated sensitizer units into the backbones or attaching the sensitizers to the backbone linkers, POPs can be developed as efficient heterogeneous photocatalysts for visible light-induced organic transformations. Due to their high stability and insolubility, POP catalysts can be easily recovered through filtration or centrifugation and recycled. POP-based photocatalysis combines visible light utility and catalyst recycling and thus represents a green and sustainable technique.

Key words: porous organic polymer, photocatalysis, heterogeneous catalysis, organic transformation, sustainability, green chemistry

Cite this article

Xu Zi-Yue, Luo Yi, Wang Hui, Zhang Dan-Wei, Li Zhan-Ting. Porous Organic Polymers as Heterogeneous Catalysts for Visible Light-Induced Organic Transformations[J]. Chinese Journal of Organic Chemistry, 2020, 40(11): 3777-3793.

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