Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (8): 3249-3255.DOI: 10.6023/cjoc202103015 Previous Articles     Next Articles



连凌翔, 尹静怡, 林彩霞*(), 叶克印, 袁耀锋*()   

  1. 福州大学化学学院 福州 350108
  • 收稿日期:2021-03-06 修回日期:2021-04-16 发布日期:2021-05-08
  • 通讯作者: 林彩霞, 袁耀锋
  • 基金资助:
    国家自然科学基金(21772023); 国家自然科学基金(21901041)

Phosphine Oxide-Directed Palladium-Catalyzed Heck-Type Functionalization of o-Carboranes

Lingxiang Lian, Jingyi Yin, Caixia Lin(), Keyin Ye, Yaofeng Yuan()   

  1. College of Chemistry, Fuzhou University, Fuzhou 350108
  • Received:2021-03-06 Revised:2021-04-16 Published:2021-05-08
  • Contact: Caixia Lin, Yaofeng Yuan
  • Supported by:
    National Natural Science Foundation of China(21772023); National Natural Science Foundation of China(21901041)

The selective functionalization of o-carboranes is a popular topic in carborane chemistry. o-Carborane has been widely used in aggregation-induced luminescent materials, nonlinear luminescent materials and other function materials due to its special 3D-aromaticity. The π conjugated systems-tethered o-carboranes could further broaden its applications in the field of luminescent materials. Herein, we have developed a palladium-catalyzed Heck-type mono-alkenylation of o-carboranes featuring phosphine oxide as the directing group.

Key words: palladium, Heck reaction, carborane, B—H activation