关键词: 分离, 化学成分, 吡喃糖, 葡萄糖, 甾族化合物, 柱色谱, 糖苷, 断节参, 萝摩科

A new glycoside, wallicoside. C61H98O26, m.p. 194-196`C, [α]D+22, was isolated from the crude glycoside mixture of cynanchum wallichii Wight. The structure of wallicoside was shown through enzymolysis and spectral analyses to be caudatin-3-o-β-D- glucopyranosyl-(1-4)-β-D-glucopyranosyl-(1-4)-β-D- olendropyranosyl-(1-4)-β-D-cymaropyranosyl-(1-4)-β-D- crmaropyranoside (6).

Key words: SEPARATION, CHEMICAL COMPOSITION, PYRANOSE, GLUCOSE, STEROIDS, COLUMN CHROMATOGRAPHY, GLYCOSIDE, WALLICOSIDE, ASCLEPIADACEAE