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化学学报
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化学学报 ›› 2007, Vol. 65 ›› Issue (22): 2533-2538. 上一篇    下一篇

研究论文

基于Au纳米通道膜分离测定芦丁

沈健，黄杉生*，彭斌，屈永霞，李瑞娜   

  1. (上海师范大学生命与环境科学学院 上海 200234)
  • 投稿日期:2007-04-19 修回日期:2007-06-28 发布日期:2007-11-28
  • 通讯作者: 黄杉生

Separation and Detection of Rutin Based on Gold Nanotubule Membrane

SHEN Jian; HUANG Sha-Sheng*; PENG Bin; QU Yong-Xia; LI Rui-Na   

  1. (Life and Environmental Science College, Shanghai Normal University, Shanghai 200234)
  • Received:2007-04-19 Revised:2007-06-28 Published:2007-11-28
  • Contact: HUANG Sha-Sheng

PDF

661

被引次数

21

采用化学沉积法将Au沉积到聚碳酸酯滤膜(PC-Mem)上, 制备了直径10 nm左右的Au纳米通道膜(Au-Mem). 实验考察了芦丁在纳米通道膜上的透过特性, 在电场作用下, 芦丁与铝形成的荷电配离子在电场力驱动下透过修饰了对巯基苯胺(PATP)的Au纳米通道膜, 实现了芦丁的分离与测定. 成功地对复方芦丁片中的芦丁分子进行了分离与测定, 回收率为96.3%～99.3%.

关键词: Au纳米通道膜, 芦丁, 分离, 测定

An electroless plating method was applied to deposit Au onto the walls of pores of polycarbonate membranes. The diameter of the Au-nanotubule is about 10 nm. The characteristics of rutin transportation through the nanotubule membranes were investigated. The complex formed by rutin and Al3＋ was transported effectively through the gold nanotubule membrane modified with p-aminothiophenol under the existence of an electric field. The method was verified by separation and determination of rutin from the rutin tablets successfully with a recovery of 96.3%～99.3%.

Key words: gold nanotubules, rutin, separation, detection