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化学学报
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化学学报 ›› 2009, Vol. 67 ›› Issue (17): 2001-2004. 上一篇    下一篇

研究论文

LaFeO3电极材料的制备和电化学性能

邓 刚 陈云贵* 陶明大 吴朝玲 沈向前
羊 恒 朱 丁

  

  1. (四川大学材料科学与工程学院 成都 610064)

  • 投稿日期:2008-11-02 修回日期:2009-02-14 发布日期:2009-09-14
  • 通讯作者: 陈云贵

Preparation and Electrochemical Property of LaFeO3 Electrode Material

Deng, Gang Chen, Yungui* Tao, Mingda Wu, Chaoling
Shen, Xiangqian Yang, Heng Zhu, Ding

  

  1. (School of Materials Science and Engineering, Sichuan University, Chengdu 610064)
  • Received:2008-11-02 Revised:2009-02-14 Published:2009-09-14
  • Contact: Yungui Chen

PDF

1295

被引次数

33

利用硬脂酸燃烧法制备了具有正交结构的LaFeO3粉末, 研究了作为Ni/MH电池的负极材料的电化学性能. 研究结果表明: LaFeO3具有充放电可逆电化学容量, 其放电容量随实验温度升高而增大, 随放电电流增大而减小; 在充放电温度为298, 313, 333和353 K条件下, 经20次循环后, XRD显示LaFeO3仍然保持钙钛矿结构, 容量分别保持在49, 110, 310和490 mAh•g－1左右, 显示了良好的循环稳定性. 计算所得的交换电流密度和离子扩散系数随温度升高而增大, 与放电容量的变化规律一致.

关键词: 镍氢电池, 阳极材料, LaFeO3, 电化学性能

LaFeO3 powders with an orthorhombic structure were prepared by a stearic acid combustion method, and its electrochemical properties were investigated as the negative electrode of Ni/MH batteries. The results show that the LaFeO3 has a reversible charge-discharge capacity, and its discharge capacity rises with the test temperature increasing and decreases with increasing discharge current density. At 298, 313, 333 and 353 K, after 20 cycles, XRD data show that the LaFeO3 remains a perovskite-type structure and the discharge capacity keeps about 49, 110, 310 and 490 mAh•g－1 respectively, indicating a good cycling stability. Exchange current density and ion diffusion coefficient rose as the temperature increased, in line with the changes of the discharge capacity of LaFeO3.

Key words: Ni/MH battery, anode material, LaFeO3, electrochemical property

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