Studies on solid state reactions of coordination compounds. 52: Synthesis of copper(II) complexes with α-amino acids by one step solid state reactions at room temperature

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (4): 358-362. Previous Articles Next Articles

Original Articles

固相配位化学反应研究 52: 室温固-固相化学反应合成氨基酸铜配合物

贾殿赠;忻新泉

南京大学配位化学研究所

发布日期:1993-04-15

Studies on solid state reactions of coordination compounds. 52: Synthesis of copper(II) complexes with α-amino acids by one step solid state reactions at room temperature

JIA DIANZENG;XIN XINQUAN

Published:1993-04-15

Abstract

Six isomers of Cu a-amino acidato complexes [trans-Cu(Gly)2.H2O, cis-Cu(Gly)2.H2O, trans-Cu(DL-Ala)2, trans-Cu(DL-Ala)2.H2O, trans-Cu(Dl-Leu)2] were synthesized by 1-step solid state reactions at room temperature The composition and conformation of products are characterized by elemental anal., IR spectra x-ray diffraction, and DTA. The reaction mechanism and the influence of trace H2O on the solid state reaction are discussed.

Key words: AMINO ACID, CYSTINE, REACTION MECHANISM, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, X-RAY DIFFRACTION ANALYSIS, GLUTAMIC ACID, ARGININE, COPPER COMPLEX, DIFFERENTIAL THERMAL ANALYSIS

CLC Number:

O611.662

Cite this article

JIA DIANZENG;XIN XINQUAN. Studies on solid state reactions of coordination compounds. 52: Synthesis of copper(II) complexes with α-amino acids by one step solid state reactions at room temperature[J]. Acta Chimica Sinica, 1993, 51(4): 358-362.

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固相配位化学反应研究 52: 室温固-固相化学反应合成氨基酸铜配合物

Studies on solid state reactions of coordination compounds. 52: Synthesis of copper(II) complexes with α-amino acids by one step solid state reactions at room temperature

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