Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (1): 69-73. Previous Articles     Next Articles

Original Articles

β-环糊精与碳酸钙结晶的相互作用

张秀英;廖照江;杨林;胡志国;蒋凯;郭玉明   

  1. 河南师范大学化学与环境科学学院,新乡(453002)
  • 发布日期:2003-01-15

Interaction between β-Cyclodextrin and Crystallization of Calcium Carbonate

Zhang Xiuying;Liao Zhaojiang;Yang Lin;Hu Zhiguo;Jiang Kai;Guo Yuming   

  1. College of Chemistry and Environmental Science, Henan Normal University,Xinxiang(453002)
  • Published:2003-01-15

Based on the basic principles of biomineralization, a novel aragonite (CaCo_3) with specific morphology was synthesized under the control of-cyclodextrin by the biomimetic method. In our experiments, the β-cyclodextrin were used as the organic matrix. The obtained composite CaCO_3 with small amount of β-cyclodextrin were characterized by X-ray powder diffraction (XRD) analysis and scanning electronic microscopy (SEM). Furthermore, according to the results of Fourier transform infrared spectroscopy (FT-IR) and measurement of conductance ratios, the possible mechanism of the interaction between β-cyclodextrin and CaCO_3 during the CaCO_3 formation process was discussed.

Key words: CRYSTALLIZE, INTERACTIONS, CYCLODEXTRIN, CALCIUM CARBONATE, MINERALIZATION, INTERFACES, MOLECULAR, IDENTIFICATION, BIONICS, SCANNING ELECTRON MICROSCOPES

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