过渡金属催化C—CN 键偶联反应的研究进展

doi:10.6023/cjoc1107281

摘要/Abstract

过渡金属催化的氰化反应是合成有机氰化物非常重要的手段之一. 综述了近年来过渡金属催化C—CN 键偶联反应的研究进展, 主要包括芳基、烯基卤化物及拟卤化物, 芳基硼酸, 烯烃, 炔烃, 芳烃等的氰化反应及其机理的探讨.

Transition-metal-catalyzed cyanation reaction is one of the most attractive modern methods for the synthesis of organic cyanides. Recent development of the transition-metal-catalyzed C—CN bonds coupling reactions is reviewed, which includes the cyanation reactions of aryl, vinyl halides and pseudohalides, arylboronic acids and alkene, alkyne, aromatic hydrocarbon. Their mechanisms are discussed.

Key words: transition metal, cyanation reaction, reaction mechanism

引用此文

严国兵, 于健, 张玲. 过渡金属催化C—CN 键偶联反应的研究进展[J]. 有机化学, 2012, 32(02): 294-303 .

Yan Guobing, Yu Jian, Zhang Ling. Recent Progress in the Research of the Transition-Metal-Catalyzed C—CN Bonds Coupling Reactions[J]. Chin. J. Org. Chem., 2012, 32(02): 294-303 .

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