铜催化不对称烯丙基烷基化反应的研究进展

doi:10.6023/cjoc1110071

摘要/Abstract

铜催化不对称烯丙基烷基化反应是一种重要的合成手性化合物的方法, 综述了铜催化不对称烯丙基烷基化反应的最新研究进展, 重点讨论了烯丙基衍生物结构、手性配体结构及亲核试剂类型等因素对该类型反应的影响.

关键词: 铜催化, 手性化合物, 烯丙基衍生物, 不对称烯丙基烷基化反应

Copper-catalyzed asymmetric allylic alkylation reaction is one of the most important methods for preparing chiral compounds. The recent progress of copper-catalyzed asymmetric allylic alkylation reaction is reviewed. Great attention is paid to the influences caused by the structure of allylic derivatives and chiral ligands and the type of nucleophiles on this kind of allylic alkylation reaction.

Key words: copper-catalysis, chiral compound, allylic derivative, asymmetric allylic alkylation reaction

引用此文

崔朋雷, 刘海燕, 张冬暖, 王春. 铜催化不对称烯丙基烷基化反应的研究进展[J]. 有机化学, 2012, 32(08): 1401-1409.

Cui Penglei, Liu Haiyan, Zhang Dongnuan, Wang Chun. Progress in Copper-Catalyzed Asymmetric Allylic Alkylation Reaction[J]. Chin. J. Org. Chem., 2012, 32(08): 1401-1409.

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