有机化学 ›› 2012, Vol. 32 ›› Issue (06): 1041-1050.DOI: 10.6023/cjoc1111041 上一篇    下一篇

综述与进展

铜催化的芳环C—H 键直接芳基化反应研究进展

刘伟, 毕艳兰   

  1. 河南工业大学粮油食品学院 郑州 450001
  • 收稿日期:2011-11-03 修回日期:2011-12-17 发布日期:2012-01-06
  • 通讯作者: 刘伟 E-mail:liuwei307@hotmail.com
  • 基金资助:
    国家自然科学基金(No. 21102036)和河南工业大学博士基金(No. 2010BS042)资助项目.

Progress in Copper-Catalyzed Direct Arylation of Aromatic C—H Bonds

Liu Wei, Bi Yanlan   

  1. School of Food Science and Technology, Henan University of Technology, Zhengzhou 450001
  • Received:2011-11-03 Revised:2011-12-17 Published:2012-01-06
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21102036) and the Doctoral Fund of Henan University of Technology (No. 2010BS042).

铜催化的芳环C—H 键直接芳基化反应已成为一种合成联芳烃化合物的重要手段, 近年来一直是有机化学和催化化学的研究热点和难点之一. 按照参与反应的底物或成键模式的不同对近年来铜催化的芳环C—H 键直接芳基化反应的研究进展进行了综述.

关键词: 铜催化, 直接芳基化反应, C—H 键活化, 联芳烃, 进展

Copper-catalyzed direct arylation of aromatic C—H bonds becomes an important method for the synthesis of biaryl compounds and also a highlight on organic and catalyst chemistry. The recent progress in copper-catalyzed direct arylation of aromatic C—H bonds is reviewed according to the different types of substrates or bond formation.

Key words: copper catalysis, direct arylation, C—H activation, biaryls, progress