有机化学 ›› 2014, Vol. 34 ›› Issue (5): 985-988.DOI: 10.6023/cjoc201401011 上一篇    下一篇

研究简报

ZSM-5催化绿色合成烯胺酮化合物

魏振中, 肖兰, 王永秋, 李品华   

  1. 淮北师范大学化学与材料科学学院 淮北 235000
  • 收稿日期:2014-01-08 修回日期:2014-03-10 发布日期:2014-03-26
  • 通讯作者: 李品华 E-mail:pphuali@126.com

Green Synthesis of Enaminones Catalyzed by ZSM-5

Wei Zhenzhong, Xiao Lan, Wang Yongqiu, Li Pinhua   

  1. School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000
  • Received:2014-01-08 Revised:2014-03-10 Published:2014-03-26

以环境友好的ZSM-5分子筛为催化剂,催化β-二羰基化合物与胺反应,绿色合成β-烯胺酮类化合物. 该方法环境友好、处理方法简单、收率高、催化剂可回收使用.

关键词: 催化, 烯胺酮, ZSM-5分子筛

It was found that ZSM-5 as a green catalyst could efficiently catalyze the reaction of various primary amines with α,β-dicarboxyl compounds to afford β-enaminones in good yields at room temperature. The method provides a novel, simple and convenient route to substitute β-enaminones from primary amines and α,β-dicarboxyl compounds. The catalyst could also be recovered easily.

Key words: catalysis, β-enaminones, ZSM-5 zeolite