有机化学 ›› 2018, Vol. 38 ›› Issue (7): 1638-1649.DOI: 10.6023/cjoc201802007 上一篇    下一篇

综述与进展

过渡金属催化N-导向羰基和醇羟基邻位C-C键活化反应的研究进展

王晶晶a, 李峰a, 于晓波c, 刘澜涛a, 丁俊汝a, 谢佩瑶a, 王建辉b   

  1. a 商丘师范学院化学化工学院 药物绿色合成河南省工程实验室 商丘 476000;
    b 天津大学理学院化学系 天津 300072;
    c 吉林化工学院材料科学与工程学院 吉林 132022
  • 收稿日期:2018-02-04 修回日期:2018-03-03 发布日期:2018-03-16
  • 通讯作者: 王建辉 E-mail:wangjingjing0918@163.com
  • 基金资助:

    国家自然科学基金(Nos.21402116,21502111)、河南省重点科技攻关(No.172102210099)和河南省高等学校重点科研(No.15A150072)资助项目.

Recent Progress in the Research of the Transition-Metal-Catalyzed N-Directed Carbonyl and Alcohol Hydroxyl ortho C-C Bonds Activation Reactions

Wang Jingjinga, Li Fenga, Yu Xiaoboc, Liu Lantaoa, Ding Junrua, Xie Peiyaoa, Wang Jianhuib   

  1. a Henan Engineering Laboratory of Green Synthesis for Pharmaceuticals, School of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000;
    b Department of Chemistry, College of Science, Tianjin University, Tianjin 300072;
    c College of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022
  • Received:2018-02-04 Revised:2018-03-03 Published:2018-03-16
  • Contact: 10.6023/cjoc201802007 E-mail:wangjingjing0918@163.com
  • Supported by:

    Project supported by the National Natural Sciences Foundation of China (Nos. 21402116, 21502111), the Key Scientific and Technological Project of Henan Province (No. 172102210099) and the Key Science Research of Education Committee in Henan Province (No. 15A150072).

过渡金属催化碳-碳键活化反应是近年来金属有机化学中非常热门且富有挑战性的研究领域之一.主要综述了近年来过渡金属(Rh,Ni,Pd和Ru)催化基于氮原子导向基团化合物碳-碳键活化与重组的研究进展,并对相关反应机理进行了探讨.

关键词: C-C键活化, 还原消除, 过渡金属, 金属化

Transition-metal-catalyzed C-C bond cleavage has been considered as one of the most interesting subject and challenging area in organometallic chemistry. The recent progress of transition-metal-catalyzed (Rh, Ni, Pd and Ru) nitrogen atom chelation-assisted C-C activation and controlled transformation is reviewed, and the mechanisms of these C-C activation reactions are also discussed.

Key words: C-C bond activation, reductive elimination, transition metals, metalation