甲酸分解制氢均相催化剂的研究进展

doi:10.6023/cjoc202003060

摘要/Abstract

甲酸（HCOOH）具有作为液氢储存材料和清洁制氢的巨大潜力.在过去的十几年中，人们不仅在开发活性更强、更稳定、选择性更强的催化剂方面取得了重大进展，而且提出了氢气释放和储存循环系统的概念.综述了均相催化剂在这一领域的最新进展，重点介绍了钌、铑、铱为代表的贵金属催化剂，同时还涉及铁、钴、镍、铜、铝等非贵金属催化剂.希望本综述对今后开发更好的甲酸脱氢催化体系提供一些见解和思路.

关键词: 氢能源, 甲酸脱氢, 均相催化, 金属催化剂

Formic acid (HCOOH) has great potential as liquid hydrogen storage materials and for clean hydrogen production. In the past decade, researchers have not only made significant progress in developing more active, stable, and selective catalysts, but also proposed the concept of the reversible system of hydrogen release and storage. This review covers the latest progress of homogeneous catalysts in this field, focusing on the noble metal based catalysts represented by ruthenium, rhodium, and iridium, as well as the non-noble metal based catalysts such as iron, cobalt, nickel, copper, aluminum and so on. It is hoped that this review will provide some insights and idea for developing better catalytic systems for the dehydrogenation of formic acid in the future.

Key words: hydrogen energy, formic acid dehydrogenation, homogeneous catalysis, metal catalyst

引用此文

刘嘉豪, 韩静杰, 易小艺, 刘超, 何飘. 甲酸分解制氢均相催化剂的研究进展[J]. 有机化学, 2020, 40(9): 2658-2668.

Liu Jiahao, Han Jingjie, Yi Xiaoyi, Liu Chao, He Piao. Research Progress of Homogeneous Catalyst for the Dehydrogenation of Formic Acid[J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2658-2668.

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