有机化学 ›› 1990, Vol. 10 ›› Issue (1): 50-54. 上一篇    下一篇

研究论文

几种氰类, 酯类取代基季铵盐吡啶卟啉及其金属配合物的合成

吴萱阶;周翔;陈彭平   

  1. 武汉大学化学系
  • 发布日期:1990-02-25

Synthesis of water soluble quaternary ammonium pyridine prophyrins and their metal complexes

WU XUANJIE;ZHOU XIANG;CHEN PENGPING   

  • Published:1990-02-25

本文选用不同碳链或取代基的卤化腈和卤代酯与中位-四(月-N-吡啶基)卟啉作用, 合成了五个季铵盐吡啶卟啉金属络合物, 经过元素分析, 红外光谱, 电子光谱, 顺磁共振谱, 核磁共振谱及差热分析, 确认了它们的结构。

关键词: 卟吩 P, 红外分光光度法, 卟吩 P, 水溶性, 吡啶 P, 卤化物, 酯, 核磁共振谱法, 有机合成, 吡啶

I (R = CH2CN, CH2CH2CN, CH2CO2Et, CH2CO2Me, CHMeCO2Et) were prepared from tetrakis(4-pyridyl)porphyrin and XR (X = Cl or Br). CoL(ClO4)4(OAc) (H2L = I) and MLX4 (M = Cu, Ni, Zn; X = ClO4, Br, Cl) were prepared and characterized by IR, NMR and ESR (Cu complexes) spectra.

Key words: PORPHINE P, PORPHINE P, PYRIDINE P, INFRARED SPECTROPHOTOMETRY, WATER SOLUBILITY, HALIDE, ESTERS, ORGANIC SYNTHESIS, NMR SPECTROMETRY, PYRIDINE

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