有机化学 ›› 2001, Vol. 21 ›› Issue (11): 986-992. 上一篇    下一篇

研究论文

氟烷基磺酰叠氮的化学反应研究

朱士正;许勇;王彦利   

  1. 中国科学院上海有机化学研究所.上海(200032)
  • 发布日期:2001-11-25

Recent developments in the research of reactions of fluoroalkanesulfonyl azides

Zhu Shizheng;Xu Yong;Wang Yanli   

  1. Shanghai Inst Organ Chem., CAS.Shanghai(200032)
  • Published:2001-11-25

氟烷基磺酰叠氮可以与一系列亲核试剂,烯胺、烯基硅醚等富电子烯烃进行独特的反应,并且能够在温和条件下将含氟基团引入到有机分子中。

关键词: 烯胺, 氮宾, 有机硅化合物, 烯基硅醚, 磺酰基, 氟代烃, 叠氮化物, 亲核试剂, 有机氟化合物

Recent development in the reactions of fluoroalkanesulfonyl azides with a series of nucleophiles, enamines, enoxysilanes and other electron-rich olefins were reviewed. In these studies, some reaction rules of fluoroalkanesulfonyl azides were found and several new methods for introducing fluoroalkanesulfonyl group into organic molecules were also accomplished.

Key words: ENAMINES, NITRENE, ORGANO SILICON COMPOUNDS, SULFONYL GROUP, FLUOROHYDROCARBON, AZIDE, NUCLEOPHILIC REAGENTS, ORGANO FLUORINE COMPOUNDS

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