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有机化学
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有机化学 ›› 2002, Vol. 22 ›› Issue (11): 840-852. 上一篇    下一篇

研究论文

1，1’—联—2—萘酚在不对称催化中的应用新进展

李小永;聂进   

  1. 华中科技大学化学系,武汉(430074)
  • 发布日期:2002-11-25

Recent advances in asymmetric catalysis using 1,1'-bi-2-naphthol

Li Xiaoyong;Nie Jin   

  1. Department of Chemistry, Huazhong University of Science and Technology,Wuhan(430074)
  • Published:2002-11-25

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589

被引次数

4

光学活性的1，1’—联—2—萘酚(BINOL)及其衍生物作为优异的手性配体应用 于不对称催化中已取得了巨大进展，显示出广阔的应用前景．对BINOL小分子和高 分子在各种不对称催化反应中的最新进展和发展方向进行了评述，并介绍了有关 BINOL的几种新型催化策略．

关键词: 不对称, 催化, 衍生物, 萘酚, 催化剂

Optically active 1,1'-bi-2-naphthol has been extensively studied as an excellent chiral ligand in asymmetric catalysis. This review describes recent advances in the applications of monomeric and polymeric binaphthols in a variety of catalytic asymmetric reactions. Several new catalytic strategies involving 1,1'-bi-2-naphthol ligand are also highlighted.

Key words: ASYMMETRY, CATALYSIS, DERIVATIVES, NAPHTHALENOL, CATALYST

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