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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (03): 239-253.    下一篇

综述与进展

γ-烷氧基-2(5H)-呋喃酮的合成、反应性及在合成中的应用

黄海波1，齐传民*,1，田作林2   

  1. (1 北京师范大学化学系 北京 100875)
    (2 长春理工大学材料与工程学院 长春 130022)
  • 收稿日期:2003-12-23 修回日期:2004-07-01 发布日期:2005-02-28
  • 通讯作者: 齐传民

Synthesis, Property and Application of 5-Alkoxy-2,5-dihydrofu-ran-2-ones

HUANG Hai-Bo1,QI Chuan-Min*,1,TIAN Zuo-Lin2   

  1. (1 Department of Chemistry, Beijing Normal University, Beijing 100875)
    (2 School of Materials & Engineering, Changchun University of Science and Technology, Changchun 130022)
  • Received:2003-12-23 Revised:2004-07-01 Published:2005-02-28
  • Contact: QI Chuan-Min

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总结了近年来一类具有-烷氧基-2(5H)-呋喃酮结构的手性化合物的合成, 反应性的研究进展, 主要包括Michael加成、环加成、对位置的亲核进攻以及此手性建构基团在不对称合成中的应用.

关键词: γ-烷氧基-2(5H)-呋喃酮, 麦克尔加成, 不对称合成, 环加成

The recent advance in synthesis, property and application of a new class of auxiliary based chiral synthons, 5-alkoxy-2,5-dihydrofuran-2-ones, is reviewed. The multifunctional compounds perform a varity of asymmetric transformations, Michael addition, cycloaddition and being attack at -position, and exhibit excellent convenience in asymmetric synthesis.

Key words: 5-alkoxy-2,5-dihydrofuran-2-one, cycloaddition, asymmetric syn-thesis, Michael addition