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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (02): 145-157.    下一篇

综述与进展

一氯二茂钛在有机合成中的应用研究

庄泽阳1,2，张维河1,2，贾学顺*,1，翟宏斌2   

  1. (1上海大学化学系 上海 200436)
    (2中国科学院上海有机化学研究所现代有机合成实验室 上海 200032)
  • 收稿日期:2004-10-10 修回日期:2005-06-10 发布日期:2006-01-21
  • 通讯作者: 贾学顺

Application of Titanocene Monochloride to Organic Synthesis

ZHUANG Ze-Yang1,2,ZHANG Wei-He1,2,JIA Xue-Shun*,1,ZHAI Hong-Bin2   

  1. (1 Department of Chemistry, Shanghai University, Shanghai 200436)
    (2 Laboratory of Modern Synthetic Organic Chemistry, Shanghai Institute of Organic Chemistry,
    Chinese Academy of Science, Shanghai 200032)
  • Received:2004-10-10 Revised:2005-06-10 Published:2006-01-21
  • Contact: JIA Xue-Shun

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被引次数

1

综述了近年来一氯二茂钛在有机合成中的应用研究, 主要涉及环氧化物的还原开环、其它还原反应、Reformatsky反应、呐醇偶联反应、不饱和金属卡宾与自由基的加成反应、制备烯糖化合物的反应、制备C-苷的反应等.

关键词: 一氯二茂钛, 有机合成, 应用

The synthetic transformations mediated by titanocene monochloride in the latest several years are reviewed. They involve mainly reductive ring opening of epoxides, other reductions, Reformatsky reactions, pinacol coupling, radical addition to unsaturated metal carbenes, and reactions of preparing glycols and C-glycosides.

Key words: organic synthesis, application, >titanocene monochloride