有机化学 ›› 2006, Vol. 26 ›› Issue (03): 299-309. 上一篇    下一篇

综述与进展

金属催化下芳基磺酸酯偶联反应的研究进展

张亮,吴劼*   

  1. (复旦大学化学系 上海 200433)
  • 收稿日期:2005-01-10 修回日期:2005-08-26 发布日期:2006-02-28
  • 通讯作者: 吴劼

Metal-Catalyzed Coupling Reactions of Arenesulphonates

ZHANG Liang,WU Jie*   

  1. (Department of Chemistry, Fudan University, Shanghai 200433)
  • Received:2005-01-10 Revised:2005-08-26 Published:2006-02-28
  • Contact: WU Jie

综述了金属催化下芳基磺酸酯作为底物参与形成碳—碳键、碳—氮键的偶联反应, 如Suzuki-Miyaura反应、Sonogashira反应等方面的研究进展.

关键词: 金属催化, 碳—氮键, 偶联反应, 碳—碳键, 芳基磺酸酯

This review summarizes recent advances in the metal-catalyzed coupling reactions of arenesulphonates with organometal reagents and amines or amides, which provide an alternative method for the construction of carbon-carbon bond and carbon-nitrogen bond.

Key words: cross-coupling reaction, transition metal catalysis, arenesulphonate, carbon-nitrogen bond, carbon-carbon bond