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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (12): 1600-1604. 上一篇    下一篇

研究简报

微波辐射条件下季戊四醇杂二缩醛(酮)的合成

袁先友*，张敏，袁霖   

  1. (湖南科技学院化学系 永州 425100)
  • 收稿日期:2007-02-10 修回日期:2007-05-18 发布日期:2007-12-04
  • 通讯作者: 袁先友

Synthesis of Hetero Diacetals and Diketals of Pentaerythritol under Microwave Irradiation

YUAN Xian-You*, ZHANG Min, YUAN Lin   

  1. (Department of Chemistry, Hunan University of Science and Engineering, Yongzhou 425100)
  • Received:2007-02-10 Revised:2007-05-18 Published:2007-12-04
  • Contact: YUAN Xian-You

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1126

被引次数

14 | 2

在微波辐射下, 以活性炭负载磷钨酸为催化剂, N,N-二甲基甲酰胺为溶剂, 将季戊四醇与醛(酮)缩合得到季戊四醇单缩醛(酮), 然后再与另一种醛缩合合成了9种季戊四醇杂二缩醛(酮). 产物经过元素分析, IR和1H NMR表征.

关键词: 季戊四醇, 微波辐射, 杂二缩醛, 杂二缩酮, 单缩酮, 单缩醛

Monoacetals or monoketals were synthesized by condensation reactions of pentaerythritol with aldehydes or ketone using phosphotungstic acid supported on active carbon as a catalyst and dimethylformamide as a solvent under microwave irradiation. Nine hetero diacetals and diketals of pentaerythritol were then synthesized by the condensation reactions of such monoacetals and monoketals with other aldehydes. All the mono- and heterodiacetals and ketals were characterized by elemental analysis, IR and 1H NMR spectra.

Key words: hetero diacetal, monoketal, hetero diketal, monoacetal, microwave irradiation, pentaerythritol