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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (02): 289-291. 上一篇    下一篇

研究简报

10-甲基吖啶盐与活泼金属在固相研磨条件下的新颖反应研究

许华建; 徐小岚; 冯乙巳*   

  1. (a合肥工业大学化学工程学院 合肥 230009)
    (b安徽医科大学化学教研室 合肥 230032)
  • 收稿日期:2008-06-06 修回日期:2008-08-05 发布日期:2009-02-20
  • 通讯作者: 冯乙巳

A Novel Reaction of 10-Methylacridinium with Reactive Metals under Grinding

Xu, Huajian; Xu, Xiaolan; Feng, Yisi*   

  1. (a School of Chemical Engineering, Hefei University of Technology, Hefei 230009)
    (b Department of Chemistry, Anhui Medical University, Hefei 230032)
  • Received:2008-06-06 Revised:2008-08-05 Published:2009-02-20
  • Contact: Feng, Yisi

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被引次数

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在固相研磨条件下, 10-甲基吖啶碘盐与碱金属Li, Na和K反应生成9,10-二氢-10-甲基吖啶(AcrH2)和10-甲基-9-吖啶酮(Acr＝O), 产率比较高. 这些反应是通过金属将电子转移给10-甲基吖啶碘盐而得以发生的.

关键词: 辅酶NADH模型物, 固相, 研磨, 电子转移

Under grinding, 10-methylacridinium iodide was reacted with alkaline metal Li, Na, or K to give 9,10-dihydro-10-methylacridine (AcrH2), and 9,10-dihydro-10-methyl-9-acridone (Acr＝O) in excellent yields, which can be understood in terms of an initial electron transfer from metal to 10-methylacridinium iodide.

Key words: solid phase, coenzyme NADH model, grinding, electron transfer