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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (02): 167-172. 上一篇    下一篇

综述与进展

非钯催化剂催化Heck反应研究进展

张磊1，崔元臣*,1,2   

  1. (1河南大学化学化工学院 开封 475001)
    (2河南大学特种功能材料实验室 开封 475001)
  • 收稿日期:2009-03-31 修回日期:2009-05-28 发布日期:2010-02-20
  • 通讯作者: 崔元臣 E-mail:yccui@henu.edu.cn

Progress in Heck Reaction Catalyzed by Non-palladium Catalyst

Zhang Lei1 Cui Yuanchen*,1,2   

  1. (1 College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001)
    (2 Laboratory of Special Functional Materials, Henan University, Kaifeng 475001)
  • Received:2009-03-31 Revised:2009-05-28 Published:2010-02-20

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2666

被引次数

11

非钯催化剂用于催化Heck反应有较多的报道. 与钯催化剂相比, 一些非钯催化剂(如镍、铜、钴等)显示了更优越的性能. 近年来, 铂、铑、钌、铁等催化体系也被用于Heck反应. 对近年来非钯催化剂用于催化Heck反应的研究进行了归纳总结.

关键词: Heck反应, 催化, 过渡金属, 卤代芳烃

Many non-palladium catalysts have been applied to Heck reactions. Compared with palladium complexes, some non-palladium catalysts (such as nickel, copper, cobalt complexes, and so on) show many advantages in application. Catalyst systems based on platinum, rhodium, ruthenium or iron were also applied to Heck reactions in recent years. In this paper, the progress in Heck reaction catalyzed by non-palladium catalyst is reviewed.

Key words: Heck reaction, catalysis, transition metal, aryl halide