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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (04): 586-590. 上一篇    下一篇

学术动态

Glaser反应研究新进展

梁浩然1,2，李建晓1，汪朝阳*,1，杨凯1   

  1. (1华南师范大学化学与环境学院 广州 510006)
    (2四川大学化学学院 成都 610064)
  • 收稿日期:2010-06-29 修回日期:2010-11-01 发布日期:2010-11-12
  • 通讯作者: 汪朝阳 E-mail:wangwangzhaoyang@tom.com

New Progress on Glaser Coupling Reaction

Liang Haoran1,2 Li Jianxiao1 Wang Zhaoyang*,1 Yang Kai1   

  1. (1 School of Chemistry and Environment, South China Normal University, Guangzhou 510006)
    (2 College of Chemistry, Sichuan University, Chengdu 610064)
  • Received:2010-06-29 Revised:2010-11-01 Published:2010-11-12
  • Contact: Zhaoyang Wang E-mail:wangwangzhaoyang@tom.com

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被引次数

8

Glaser偶联反应是合成二炔化合物的重要反应, 广泛应用于有机合成、材料化学等领域. 介绍了近年来Glaser偶联反应中溶剂、氧化剂、底物等领域的研究新进展, 指出Glaser偶联反应在不断加深其各方面绿色化研究的同时, 多功能团底物的Glaser偶联反应与不对称的Glaser偶联反应也值得关注.

关键词: Glaser偶联反应, 溶剂, 氧化剂, 底物, 绿色化学

Glaser coupling reaction has played an important role in the synthesis of 1,3-diynes, and has been extensively used in organic synthesis and material chemistry. The new research progresses on the Glaser coupling reaction involving in solvent, oxidant, and substrate were reviewed in this paper. It was pointed out that various researches on green chemistry of Glaser coupling reaction should be intensified continuously in the future. At the same time, the research on the Glaser coupling reaction of substrate with polyfunctional groups and the unsymmetric Glaser coupling reaction based on different substrate is also noteworthy.

Key words: glaser coupling reaction, solvent, oxidant, substrate, green chemistry