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有机化学
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有机化学 ›› 2001, Vol. 21 ›› Issue (3): 191-199. 上一篇    下一篇

研究论文

非离子水溶性膦配体的合成及其应用进展

刘晓忠;王艳华;缪强;金子林   

  1. 大连理工大学精细化工国家重点实验室
  • 发布日期:2001-03-25

Review on the synthesis of nonionic water-soluble phosphines and their application in biphasic catalysis

Liu Xiaozhong;Wang Yanhua;Miao Qiang;Jin Zilin   

  • Published:2001-03-25

PDF

423

被引次数

5

按非离子水溶性膦配体的发展特点，就羟基取代膦配体、天然碳水化合物为母体的膦配体、聚醚基取代的膦配体、具手性中心的膦配体、高分子负载型膦配体、温控相转移膦配体、环糊精改性的膦配体等类型的非离子水溶性膦配体的合成及其在两相催化中的应用作一综述。

关键词: 非离子型, 加氢, 甲酰化, 过渡金属络合物, 水溶性, 多相催化, 膦, 配体

The paper categorized nonionic water-soluble phosphines reported in the literature into hydroxy-subsituted phosphines, natural carbohydrate-supported phosphines, polyether-substitued phosphines, chiral phoshines, polymer-supported phosphines, thermoregulated phase- transfer catalytic phosphines and cyclodextrin-modifed ligands, and reviewed on the synthesis of the phosphines and their application in aqueous biphasic catalysis .

Key words: NON-IONIC EMULSIFIERS, HYDROGENATION, FORMYLATION, TRANSITION METAL COMPLEX, WATER SOLUBILITY, HETERGENOUS CATALYSIS, PHOSPHINE, LIGANDS

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